Chemistry NCERT Exemplar Solutions Class 11th Chapter Twelve

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alok kumar singh

Contributor-Level 10

29. (i) It does not show resonance due to the absence of π electrons. 

(ii) It shows resonance due to the presence of lone pairs on the Nitrogen atom and π electrons on the C = O bond. Hence, amide can be represented by three resonating structures.

(iii) In this structure, the lone pair of electrons present on Nitrogen atom, is not conjugated with the π electrons of double bond. Hence, it does not show resonance.

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alok kumar singh

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28.

S.No.

Inductive Effect

Resonance      Effect

1



It involves the displacement of σ electrons in saturated compounds.

It involves displacement of π electrons or Lone pair of electrons in unsaturated and conjugated compounds.

2

In inductive     effect, there     is slight

displacement of σ electrons and

partial positive or negative charge develops.

In this effect, there is complete transfer of  π electrons and as a result, complete positive or negative charge develops.

3

Inductive effect can move only up to 3 to 4 carbons.

In  this case,     movement       of electrons along the length          a conjugated system takes place.

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alok kumar singh

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(i) In this case CH3+ is the most stable species because replacement of H atom by Br atom (-Inductive effect) increases positive (ii

(ii)  is most stable because negative charge on carbon atom is dispersed due to -I effect of Cl. More Cl atoms, more dispersal of negative charge and more stabilized.

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alok kumar singh

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 is most stable because negative charge on carbon atom is dispersed due to -I effect of Cl. More Cl atoms, more dispersal of negative charge and more stabilized.

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alok kumar singh

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27. In this case CH3+ is the most stable species because replacement of H atom by Br atom (-Inductive effect) increases positive charge on the carbon atom and destabilizes the species.

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alok kumar singh

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This is a short answer type question as classified in NCERT Exemplar

SO3 acts as an electrophile as in this, three highly electronegative oxygen atoms are attached to the sulphur atom which makes it electron deficient. It can be shown by resonance that it gets positive charge and acts as an electrophile.

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alok kumar singh

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26. (b)CH3 -CH2 -CH (Br)-CH2 -CH2 -CH2 -COOH 

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alok kumar singh

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26. CH3 -CH2 -CH2 -CH2 -CH2 -CH2 -CH2Br 

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