Chemistry

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A
alok kumar singh

Contributor-Level 10

This is a Short Answer Type Questions as classified in NCERT Exemplar

(i) 3-Phenylprop-2-ene-1-al.

(ii) Cyclohexanecarbaldehyde

(iii) 3-Oxopentan-1-al

(iv) IUPAC name: But-2-enal

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alok kumar singh

Contributor-Level 10

This is a Short Answer Type Questions as classified in NCERT Exemplar
Ketone group should have methyl ketone in the iodoform test. Yellow PPT is formed when the ketone, base, and iodine react. If it's methyl ketone, the test will come back positive. Pentan-2-one and pentan-3-one are the methyl ketones.

 

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alok kumar singh

Contributor-Level 10

This is a Short Answer Type Questions as classified in NCERT Exemplar

Butanol is a four-carbon aldehyde, with the aldehyde group on the fourth carbon. It has a functional group and a carbonyl group that interacts dipole-dipole. Because butanol possesses a polar O-H bond, it exhibits intermolecular H bonding, which is not feasible in butanal due to the lack of a polar bond. The boiling point of butanol is higher than that of butan-1-ol.

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alok kumar singh

Contributor-Level 10

This is a Long Answer Type Questions as classified in NCERT Exemplar

Ans: Liquid 'A' reduces ammoniacal silver nitrate and 'B' is a ketone which forms white crystalline solid on treatment with hydrogen sulphite

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alok kumar singh

Contributor-Level 10

 This is a Long Answer Type Questions as classified in NCERT Exemplar

Ans: Functional isomers

Compound I will react faster with HCN due to less steric hindrance and greater positive charge on carbon atom of carbonyl group. Two methyl groups increase electron density on carbonyl carbon in compounds II hence the rate of nucleophilic attack is less.
Mechanism of the reaction:

 

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alok kumar singh

Contributor-Level 10

This is a Long Answer Type Questions as classified in NCERT Exemplar

Ans: The aromatic compound 'A' does not give Tollen's reagent test, it is not an aromatic aldehyde. As it responds to an iodoform test called methyl ketone.

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alok kumar singh

Contributor-Level 10

This is a Long Answer Type Questions as classified in NCERT Exemplar

Ans:

Fehling's test is positive when compound 'B' is used. It gives an iodoform test and proves that it is an aldehyde. Because it fails Fehling's test, compound 'C' is a ketone.

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Pallavi Pathak

Contributor-Level 10

According to the de Broglie equation, the particles like electrons have wave-like properties. The quantum mechanical model foundation is laid by this concept and it also explains the stability of electron orbits using wave behavior.

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Pallavi Pathak

Contributor-Level 10

The hydrogen atom can be accurately explained by Bohr's model. However, it does not account for shielding effects, electron-electron interactions, and the wave nature of electrons for multi-electron atoms.

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Pallavi Pathak

Contributor-Level 10

Quantum numbers describe the unique position and energy of an electron in an atom. These are a set of four numbers and are important for predicting chemical behavior and understanding the distribution of electrons in orbitals.

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