The S-block Elements

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Vishal Baghel

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(a) Smaller the size of the ion, more highly it is hydrated and hence greater is the mass of the hydrated ion and thus the ionic mobility become lesser. The extent of hydration decreases in the order.
Li+ < Na+ + < Rb+ < Cs+
Thus the mobility of Cs+ will be the highest

(b) Due to its smaller size lithium can form nitride directly as an exceptional behaviour unlike other alkali metals.

(c) It is because reduction potential depends upon sublimation energy, ionisation energy and hydration energy. Their resultant is almost constant for these ions.

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Vishal Baghel

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(i) 2Na + 2H2O → 2NaOH + H2
(ii) 2Na + O2 → Na2O2
(iii) Na2O2 + 2H20 → 2NaOH + H2O2

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Vishal Baghel

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Sodium:

  • Na+ions participate in the transmission of nerve signals, in regulating the flow of water across cell membranes.
  • In the transport of sugars and amino acids into cell.

Potassium:

  • K+ions activate many enzymes.
  • Participate in the oxidation of glucose to produce ATP.

Magnesium:

  • All enzymes that utilise ATP in phosphate transfer require magnesium as a cofactor.
  • Mg is the central metal ion present in chlorophyll pigment in plants.

Calcium:

  • Ca2+ ions are present in bones.
  • plays important roles in neuromuscular function.

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Vishal Baghel

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It is due to high lattice energy of LiF as compared to LiCl.
LiCl is soluble in water because its hydration energy is higher than its lattice energy.

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Vishal Baghel

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Li+ can polarize water molecules easily than the other alkali metal ions because of its small size.

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Vishal Baghel

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Limestone:

  • A raw material for cement.
  • It is used as a building material in the form ofmarble and in the manufacture of quick lime.
  • used in the manufactureof high quality paper. It is also used as anantacid, mildabrasive in tooth paste, aconstituent of chewing gum, and a filler incosmetics.

Cement:

  • It is used in concrete and reinforcedconcrete, in plastering and in the construction
  • of bridges, dams and buildings

Plaster of Paris:

  • It is used in the building industry as well as plasters.
  • It is usedfor immobilising the affected part of organ wherethere is a bone fracture or sprain.
  • It is alsoemployed in dentistry, in ornamental work andfor making ca
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Vishal Baghel

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Since group 1 hydroxides and carbonates due to large size contain higher hydration energy than the lattice energy so, they are easily soluble in water. Whereas, in magnesium and calcium due to small size their lattice energy dominates over hydration energy they are sparingly soluble in water.

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Vishal Baghel

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BeCl2  (vapour)
In the vapour state, it exists as a chloro-bridged dimer.

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Vishal Baghel

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(i) Caustic soda
It is used in (a) the manufacture of soap, paper, artificial silk and a number of chemicals, (b) in petroleum refining, (c) in the purification of bauxite, (d) in the textile industries for mercerising cotton fabrics, (e) for the preparation of pure fats and oils, and (f) as a laboratory reagent.

(ii) Sodium carbonate
(a) It is used in water softening, launderingand cleaning.

(b) It is used in the manufacture of glass, soap, borax and caustic soda.

(c) It is used in paper, paints and textileindustries.

(d) It is an important laboratory reagent bothin qualitative and quantitative analysis

(iii) Quick lime

(a) It is an i

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Vishal Baghel

Contributor-Level 10

(i) Magnesium is burnt in air to form magnesium oxide and magnesium nitride.

2Mg + O2 → 2MgO

3Mg + N2 → Mg3N2.

 

(ii) Quick lime is heated with silica above 1273 K to obtain calcium silicate

CaO+SiO2 → CaSiO3.

 

(iii) Chlorine reacts with slaked lime to form calcium hypochlorite- a constituent of bleaching powder.

2Ca (OH)2 + 2Cl2 → CaCl2 + Ca (OCl)2 + 2H2O.

 

(iv) Calcium nitrate is heated to obtain CaO, NO2 and O2.

2Ca (NO3)2→2CaO+4NO2+O2.

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