Chemistry Hydrocarbon

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5 months ago

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R
Raj Pandey

Contributor-Level 9

C? H? → possible structure of C? H? are; CH? -C (CH? )=CH? and CH? -CH=CH-CH?
(Unsaturation factor = 1)
Ozonolysis of CH? -C (CH? )=CH? gives acetone (B) and formaldehyde.
Oxidation of CH? -C (CH? )=CH? with KMnO? /H? gives acetone (B) and CO?
The question states it gives C? H? O (B). Hence the alkene is 2-Methylpropene (A).
[Reaction scheme showing ozonolysis and permanganate oxidation of 2-methylpropene]

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A
alok kumar singh

Contributor-Level 10

Density ∝ molar mass, as size of given molecules is nearly same

 

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R
Raj Pandey

Contributor-Level 9

(a) Phenol with Br? / H? O gives 2,4,6-tribromophenol. (High ionisation due to polar solvent and high activation of ring)
(b) Phenol with Br? in CS? /CHCl? /FeBr? gives a mixture of o- and p-bromophenol, with p-bromophenol as the major product. (less ionisation due to non- polar solvent)
[Chemical reactions showing bromination of phenol under different conditions]

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alok kumar singh

Contributor-Level 10

Conjugate base is highly stable.
Acidic strength ∝ stability of conjugate base.
So,  cyclopentadiene is most acidic.

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A
alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

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V
Vishal Baghel

Contributor-Level 10

Kindly consider the following figure

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V
Vishal Baghel

Contributor-Level 10

C x H y ( g ) + ( x + y 4 ) O 2 ( g ) x C O 2 ( g ) + y 2 H 2 O ( l )

V 6V - -

- - 4V

Volume of CO2 = 4 * V C x H y

Vx = 4V

x = 4

Volume of O2 = 6 * V C x H y

V ( x + y 4 ) = 6 V

4 + y 4 = 6

y = 8

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5 months ago

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V
Vishal Baghel

Contributor-Level 10

Hence

CH3 – CH2 – CHO can't be formed.

In case of unsymmetrical alkynes, more positive charge stabilizing carbon attacked by H2O and finally converted into carbonyl.

New answer posted

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V
Vishal Baghel

Contributor-Level 10

Kindly consider the following figure

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P
Payal Gupta

Contributor-Level 10

With CO2 gas water forms carbonic acid

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