Chemistry

Both lithium and magnesium are harder and lighter than other elements in the respective groups.

Lithium and magnesium react slowly with water. Their oxides and hydroxides are much less soluble and their hydroxides decompose on heating. Both form a nitride, Li₃N and Mg₃N₂, by direct combination with nitrogen.

The oxides, Li₂O and MgO do not combine with excess oxygen to give any superoxide. (iv) The carbonates of lithium and magnesium decompose easily on heating to form the oxides and CO₂. Solid hydrogen carbonates are not formed by lithium and magnesium.

Both LiCl and MgCl₂are soluble in ethanol.

Both LiCl and MgCl₂are deliquescent and crystallise from aqueous solution as hydrates, LiCl·2H_2^O and MgCl₂6H₂

1. Physical appearance: All the alkali metals are silvery white, soft and light metals.
2. Density: Because of the large size, these elements have low density which increases down the group except for potassium which is lighter than sodium (most likely due to an unexpected increase in the atomic size.).
3. The melting and boiling points of the alkali metals are low indicating weak metallic bonding due to the presence of only a single valence electron in them.
4. Atomic volume:The atomic volume, atomic and ionic radii rise as the group number reduces from Li to Cs.
5. Melting and boiling points:The weak crystal lattice bonding causes low melting and boiling points of all alkali metals.

6. The alkali metals and their salts impart characteristiccolour to an oxidizing flame and thus can be detected bythe respective flame tests and can bedetermined by flame photometry or atomic absorption spectroscopy.
7. These elements whenirradiated with light, the light energy absorbedmay be sufficient to make a can atom lose electron.This property makes caesium and potassiumuseful as electrodes in photoelectric cells.
8. Ionisation power:Alkali metals have the lowest initial ionisation energy among their periods.The ionisation energy drops as one moves down the group.
9. Electropositivity character:Alkali metals are highly electropositive or metallic in nature, and this feature grows in strength as the alkali metals progress from Li to Cs.
10. Electrode potentials:Alkali metals are strongly electropositive and oxidise easily in water, releasing hydrogen gas.
11. Reducing nature:Due to their low ionisation energies, alkali metals are good reductants. Their lowering character is Na, Cs, Rb, K, Li (in aqueous solution).
12. Electronegativity:The electronegativity of alkali metals decreases as one moves down the periodic table.
13. Oxidation states:The outermost valence shell of all alkali metals contains only one electron. After the penultimate shell is completed, these atoms lose one electron to the nearest inert gas. As a result, the monovalent elements have an oxidation state +1.
14. Hydration of ions:All alkali metal salts (excluding lithium) are ionic and soluble in water due to a strong hydration tendency of the alkali metal cations;
15. Colour of flame:All alkali metals and associated salts give a non-luminous flame a distinct colour.Because of the absorption of energy, the electrons of an alkali metal and its salt are stimulated to higher energy levels when placed in a burning flame. This is a volatile state. Thus, a specific light colour is released as the electrons return towards the ground state. As one moves from Li to Cs, the ionisation energy decreases, increasing the frequency of the light emitted.
16. The photoelectric effect:Alkali metals, in particular K and Cs, have a photoelectric effect because of their low ionisation activity and work function.
17. The electrical conductivity:Since the valence electrons of all alkali metals may freely travel through the crystal structure, they are excellent heat and electric conductors. Electrical conductivity increases as one moves down the group.

Common chemical features of alkali metals are:

The alkali metals are highly reactive due totheir large size and low ionization enthalpy. Thereactivity of these metals increases down thegroup.

1. Reactivity towards air: The alkali metalstarnish in dry air due to the formation oftheir oxides which in turn react withmoisture to form hydroxides. They burnvigorously in oxygen forming oxides.Because oftheir high reactivity towards air and water, alkali metals are normally kept in kerosene oil.
2. Reactivity towards water: The alkalimetals react with water to form hydroxideand dihydrogen. Reaction of lithium with water is less vigorous thanthat of sodium due to itssmall size and very high hydration energy.Other metals of the group react explosivelywith water.They also react with proton donors suchas alcohol, gaseous ammonia and alkynes.
3. Reactivity towards dihydrogen: Thealkali metals react with dihydrogen atabout 673K to formhydrides. All the alkali metal hydrides areionic solids with high melting points.
4. Reactivity towards halogens: The alkalimetals readily react vigorously withhalogens to form ionic halides, butlithium halides are somewhatcovalent due to highpolarisation capability of lithium ion.
5. Reducing nature: The alkali metals arestrong reducing agents, lithium being themost and sodium the least powerful. With the small size of its ion, lithium hasthe the highest hydration enthalpy whichaccounts for its high negative E0 value andits high reducing power.
6. Solutions in liquid ammonia: The alkalimetals dissolve in liquid ammonia givingdeep blue solutions which are conductingin nature.