Class 11th

Match the reactions given in Column I with the reaction types in Column II.

Match the following reactants in Column I with the corresponding reaction products in Column II.

∆_fU $°$ of formation of CH₄ (g) at certain temperature is –393 kJ/mol. The value of ∆_fH $°$ is

(i) zero

(ii) < _f U $°$

(iii) > ∆_f U $°$

(iv) Equal to ∆_fU $°$

Match the hydrocarbons in Column I with the boiling points given in Column II.

During complete combustion of one mole of butane, 2658 kJ of heat is released. The thermochemical reaction for above change is

(i) 2C₄H₁₀(g) + 13O₂(g) → 8CO₂(g) + 10H₂O(l) ∆_c H = –2658.0 kJ/mol

(ii) C₄H₁₀(g) $\frac{13}{2}$ +  O₂ (g) → 4CO₂ (g) + 5H₂O (g) ∆_c H = –1329.0 kJ/mol

(iii) C₄H₁₀(g) $\frac{13}{2}$ +  O₂ (g) → 4CO₂ (g) + 5H₂O (l) ∆_c H = –2658.0 kJ/mol

(iv) C₄H₁₀ (g) $\frac{13}{2}$ + O₂ (g) → 4CO₂ (g) + 5H₂O (l) ∆_c H = +2658.0 kJ/mol

Match the reagent from Column I which on reaction with 

CH₃ – CH=CH₂ gives some product given in Column II as per the codes given below:

The molecules having dipole moment are __________. 

(i) 2,2-Dimethylpropane 

(ii) Trans-Pent-2-ene 

(iii) Cis-Hex-3-ene 

(iv) 2, 2, 3, 3 - Tetramethylbutane.

Four structures are given in options (i) to (iv). Examine them and select the aromatic structures.

(i) CH₃—O—CH₂^⊕ is more stable than CH₃—CH₂^⊕

(ii) (CH₃)₂CH^⊕ is less stable than CH₃—CH₂—CH₂^⊕

(iii) CH₂=CH—CH₂^⊕ is more stable than CH₃—CH₂—CH₂^⊕

(iv) CH₂=CH^⊕is more stable than CH₃—CH₂^⊕

In an electrophilic substitution reaction of nitrobenzene, the presence of nitro group ________. 

(i) Deactivates the ring by inductive effect. 

(ii) Activates the ring by inductive effect. 

(iii) Decreases the charge density at ortho and para position of the ring relative to meta position by resonance. 

(iv) Increases the charge density at meta position relative to the ortho and para positions of the ring by resonance