Class 12th

Na+ C + N + S ®NaSCN

Fe³⁺ + SCN^– $\stackrel{}{\to }$ $\underset{Bloodred}{{\left[Fe\left(SCN\right)\right]}^{2+}}$

Potassium permanganate in alkaline medium oxidise lodide to lodate.

$2Mn{O}_4^{-}+H_{2}O+I^{\Theta }\stackrel{}{\to }2Mn{O}_2+2O{H}^{\Theta }+I{O}_3^{\Theta }(A)$            

Compound A is  . Therefore, oxidation state of 1is + 5.

From structure it is clear [CO₂ (CO)₂] has bridging carbonyl ligand.

In presence of light allylic substitution occur.

In presence of CCl₄, addition reaction will occur.

KMnO₄ decomposes upon heating at 513 K and forms K₂MnO₄ and MnO₂.

2KMnO₄  K₂MnO₄ + O₂ + MnO₂

  $\overrightarrow{a}+5\overrightarrow{b}$  is collinear with $\overrightarrow{c}$  

⇒   $\overrightarrow{a}+5\overrightarrow{b}$ = $\overrightarrow{c}$           …(1)

$\overrightarrow{b}+6\overrightarrow{c}$ is collinear with $\overrightarrow{a}$  

⇒   $\overrightarrow{b}+6\overrightarrow{c}=\mu \overrightarrow{a}$               …(2)

From (1) and (2)

  $\overrightarrow{b}+6\overrightarrow{c}=\mu \left(\lambda \overrightarrow{c}-5\overrightarrow{b}\right)$          

-> $\left(1+5\mu \right)\overrightarrow{b}+\left(6-\lambda \mu \right)\overrightarrow{c}=0$

$?\overrightarrow{b}$ and $\overrightarrow{c}$  are non-collinear

-> 1 + 5m = 0 $\mu =\frac{-1}{5}$  and 6 – lm = 0 Þ lm = 6

-> l = – 30

Now,

$\overrightarrow{b}=6\overrightarrow{c}=\frac{-1}{5}\overrightarrow{a}$

$5\overrightarrow{b}+30\overrightarrow{c}=-\overrightarrow{a}$

$\begin{array}{cc}\hfill \overrightarrow{a}+5\overrightarrow{b}+30\overrightarrow{c}=0\hfill & \hfill \overrightarrow{a}+\alpha \overrightarrow{b}+\beta \overrightarrow{c}=0\hfill \end{array}]$

On comparing

α = 5, β = 30 ⇒ α + β = 35

y (x) = 2^x – x²

y? (x) = 2x log 2 – 2x

M = 3

N = 2

M + N = 5

${\displaystyle \int \frac{\left(sinx-cosx\right)si{n}^{2}x}{tanx\left(si{n}^{3}x+co{s}^{3}x\right)}dx}$

${\displaystyle \int \frac{\left(sinx-cosx\right)sinxcosx}{si{n}^{3}x+co{s}^{3}x}dx}$ , put sin³x + cos³x = t(3 sin²x*cosx – 3cos²xsinx) dx = dt

-> $\frac{1}{3}{\displaystyle \int \frac{dt}{t}}$

$=\frac{lnt}{3}+c$

$=\frac{ln\left|si{n}^{3}x+co{s}^{3}x\right|}{3}+c$

$f\left(x\right)=\frac{\left(2^x+2^{-x}\right)tanx\sqrt[]{ta{n}^{-1}\left(2x^2-3x+1\right)}}{{\left(7x^2-3x+1\right)}^3}$

$f\left(x\right)=\left(2^x+2^{-x}\right).tanx.\sqrt[]{ta{n}^{-1}\left(2x^2-3x+1\right)}.{\left(7x^2-3x+1\right)}^{-3}$

$f\text{'}\left(x\right)=\left(2^x+2^{-x}\right).se{c}^{2}x.\sqrt[]{ta{n}^{-1}\left(2x^2-3x+1\right)}.{\left(7x^2-3x+1\right)}^{-3}+tanx.\left(Q\left(x\right)\right)$

$f\text{'}\left(0\right)=2.1\sqrt[]{\frac{\pi }{4}}.1$

$=\sqrt[]{\pi }$