Thermal Properties of Matter

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Payal Gupta

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11.15 The gases listed above are diatomic. Besides the translational degree of freedom, they have other degrees of freedom. Heat must be supplied to increase the temperature of these gases. This increases the average energy of all the modes of motion. Hence the molar specific heat of diatomic gases is more than that of monatomic gases.

If only rotational mode of motion considered, then the molar specific heat of a diatomic gas

52 R = 52*1.98 = 4.95 cal mo1–1 K–1

With the exception of Chlorine, all the observations given above agrees with ( 52 R). This is because at room temperature, chlorine also has vibrational modes

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Payal Gupta

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11.14 Mass of the metal, m = 0.20 kg = 200 g

Initial temperature of the metal,  T1 = 150 °C, Final temperature of the metal,  T2 = 40 °C

The water equivalent mass of the calorimeter, m' = 0.025 kg = 25 g

Volume of water, V = 150 cm3

Mass of water, M at T = 27 °C, = 150 *1=150g

Fall in metal temperature,  ?  T = T1-T2 = 150 – 40 = 110 °C

Specific heat of water,  Cw = 4.186 J/g/ ° K

Let the specific heat of metal = C

Then, heat loss by the metal,  θ = mC ?  T ……. (i)

Rise in the water of the calorimeter system ?  T' = 40 – 27 = 13°C

Heat gained by the water and calor

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Payal Gupta

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11.13 Mass of the copper block, m = 2.5 kg = 2.5 *103 gm

Rise in temperature of the copper block,  ?  T = 500°C

Specific heat of the copper, C = 0.39 g–1 K–1

Heat of fusion of water, L = 335 J g–1

The maximum heat the copper block can lose, Q = mc ?  T = 2.5 *103*0.39*500 = 487500 J

Let m1 gm be the mass of the ice, which will melt because of the copper block.

Heat gained by ice block = Q = m1L

m1=QL = 487500335 g = 1455.22 gm = 1.45 kg

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Payal Gupta

Contributor-Level 10

11.12 Power of the drilling machine, P = 10 kW= 10 *103 W

Mass of the Aluminium block, m = 8.0 kg = 8 *103 gm

Time for which the machine is used, t = 2.5 minute = 2.5 *60 s = 150 s

Specific heat of Aluminium, c = 0.91 J/gK

Let the rise of temperature in the block after drilling be δ T

Total energy consumed by the drilling machine= P *t = 10 *103*150 J = 1.5 *106 J

It is given 50% of energy is useful.

So useful energy,  ? Q = 50% of Pt= 0.5 * 1.5 *106= 7.5 *105 J

We know,  ? Q = mc ?  T or T = ? Qmc = 7.5*1058*103*0.91 = 103 ?

Therefore 2.5 minute drilli

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Payal Gupta

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11.11 Coefficient of volume expansion of glycerin, αV = 49 *10-5 /K

Rise in temperature, ?T = 30°C

Fractional change in volume = ?VV

We can write, ?VV = αV*?T = 49 *10-5*30 = 0.0147 ……(i)

If the final volume is V2 and initial volume is V1 , then

?VV = V2-V1V1

V2=mρ2 and V1=mρ1 where ρ1 & ρ2 are initial and final densities

?VV = V2-V1V1 = ρ2-ρ1ρ1 = fractional change in density = 0.0147 = 1.47 * 10-2

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Payal Gupta

Contributor-Level 10

11.10 Initial temperature, T1 = 40.0°C, Final temperature, T2 = 250°C, ? T = T2 - T1 = 210°C

Initial length of the brass rod at T1 , lb = 50 cm, Initial diameter of the brass rod at T1 , d1 = 3 mm

Length of the steel rod ls=50cm

For the expansion of the brass rod, we have:

Changeinlength(?lb)Originallength(lb) = αb?T , then ?lb = 50 *2.0*10-5*210 = 0.21 cm

For the expansion of the steel rod, we have:

Changeinlength(?ls)Originallength(ls) = αb?T , then ?ls = 50 *1.2*10-5*210 = 0.126 cm

Total change in length = 0.21 + 0.126 = 0.336 cm

Since the rods are free at the end, no thermal stress developed.

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Payal Gupta

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11.9 Initial temperature, T1 = 27°C, Length of the wire l1 at T1 = 1.8 m

Final temperature, T2 = -39°C

Diameter of the wire, d = 2.0 mm = 2 *10-3 m

Coefficient of linear expansion of brass, α=2*10-5 /K

Youngs' modulus of brass, Y = 0.91 *1011 Pa

Let the tension developed be F

We know Youngs' modulus = StressStrain = FA?LL=Y

*?LL = FA or F = AY?LL

Here, A = cross-sectional area of the wire = π4d2 = π4(2*10-3)2 m2 = 3.1416 *10-6m2

Now ?L can be written as ?L = αL(T2-T1) = ( 2*10-5)*L*(-39-27) = -1.32 *10-3 L

Substituting all values, we get

F = (3.1416 *10-6*0.91*1011*(-1.32*10-3) = -377.37 N

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Payal Gupta

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11.8 Initial temperature, T1 = 27.0 °C, Initial diameter of the hole, d1 = 4.24 cm

Final temperature, T2 = 227.0 °C, Final diameter of the hole =d2

Coefficient of linear expansion of copper, αcopper = 1.70 *10-5 K–1

We know

Changeinarea(?A)Originalarea(A) = β? T where β is the coefficient of superficial expansion, β=2αcopper

(πd224-πd124)πd124 = 2αcopper? T

d22-d12d12 = 2αcopper? T

d22d12 - 1= 2αcopperT2-T= 2 * 1.70 *10-5 (227-27) = 6.8 *10-3

d22=1.0068*4.24*4.24

d2 = 4.2544 cm

So change in diameter = 4.2544 – 4.24 = 0.01439 cm

Diameter increase by 1.44 *10-2 cm

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Payal Gupta

Contributor-Level 10

11.7 Given, temperature T1 = 27 °C = 27 + 273.16 K = 300.16 K

Outer dia of the shaft at temp T1 ,  d1 = 8.7 cm

Diameter of the central hole of the wheel,  d2 = 8.69 cm

The change in diameter, Δd= d2-d1= 8.69 – 8.7 = - 0.01 cm

After the shaft is cooled in dry ice, its temperature becomes T2 . It can be calculated from the relation

Δd= d1*αsteel  ( T2-T1)

-0.01 = 8.7 *1.20*10-5 (T2-300)

T2-300 = -95.78

T2 = 204.22 K = -68.94 ?

New answer posted

4 months ago

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Payal Gupta

Contributor-Level 10

11.6 Length of the steel tape, l = 1 m = 100 cm, At temperature T = 27 ° C

Coefficient of linear expansion of steel α = 1.2 *10-5 / K

Let l1=63cm be the length of the steel rod at temperature T1 = 45.0 °C and

l2 be the length of the steel rod and l' be the length of the steel tape at 45.0 °C

We have l' = l + αl (T1-T) = 100 + 1.2 *10-5*100*  (45-27) = 100.0216 cm

l2 can be calculated as l2 = l'l*63 = 63.0136 cm

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