Chemistry NCERT Exemplar Solutions Class 12th Chapter Six

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2 months ago

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A
alok kumar singh

Contributor-Level 10

KCN is used as depressant for ZnS. While Au and Ag, cyanide process (leaching) is used.

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alok kumar singh

Contributor-Level 10

Moles of Fe3O4 = 4.64*103232=20

Moles of CO = 2.52*10328=90

So limiting reagent = Fe3O4

So moles of Fe formed = 60

Weight of Fe = 60 * 56 = 3360

 

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alok kumar singh

Contributor-Level 10

ΔH=ΔU+ΔngRT

ΔH=59.6+1*8.314*300*103=57.10kJ/mol

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alok kumar singh

Contributor-Level 10

Al is extracted from Al2O3.2H2O  i.e, Bauxite ore.

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Payal Gupta

Contributor-Level 10

Siderite – FeCO3 (ore of iron)

Calamine – ZnCO3 (ore of zinc)

Malachite – CuCO3.Cu (OH)2 (ore of copper)

Cryolite – Na3AlF6 (ore of aluminium)

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Vishal Baghel

Contributor-Level 10

State functions are

(a) Internal energy

(b) Volume

(c) Enthalpy

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Vishal Baghel

Contributor-Level 10

 N2+O2? VeryhighTemp2NO

Reaction is endothermic and required very high temperature for comobination

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alok kumar singh

Contributor-Level 10

U and H are temperature dependent

CP, m-CV, m=R  (for 1 mole of ideal gas)

dU=CVdt

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Vishal Baghel

Contributor-Level 10

 ΔG=ΔHTΔS

Δ S increases then (Ve) value of ΔG increases and it is easy to reduce. Entropy of liquid is greater than solid. On melting, entropy increases and ΔG becomes more negative.

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alok kumar singh

Contributor-Level 10

(a) In extraction of iron lime stone is added on a flux

CaCO3? CaO+CO2CO2+SiO2? CaSiO3

(b) Extraction of silver

Ag+NaCN?  anionic complex Ag (CN)2-

(c) Nickel is purified by Mond's process

(d) Zr and Ti are purified by Van Arkel method by converting to volatile iodide.

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