Chemistry NCERT Exemplar Solutions Class 12th Chapter Two

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2 months ago

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Vishal Baghel

Contributor-Level 10

  [Co (H2O)6]2++NH3 (excess) [Co (NH3)6]3++6H2ODiamagneticnature

Co3+3d64s0

t2g6eg0  (form of paired electron)

No. of electron in t2g = 6

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Vishal Baghel

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 Kcat=Ae (Ea)catRTandKuncat=Ae (Ea)uncatRT

KcatKuncat=e (Ea)uncat (Ea)catRT=e10*10008.314*300=e4.009=ex

x=4

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Vishal Baghel

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cell reaction is ;

Cu (s)+Sn (aq)2+Cu (aq)+++Sn (s)

Q= [Cu++] [Sn++]=0.010.001andn=2

Ecell=Ecello0.0592log0.010.001

=0.480.0592log10=0.509

=983.33*101KJ/mole

the nearest integer = 983

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Vishal Baghel

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Hl? 12H2+12l2

t = eq1 - α2 α2 [α=0.4]

Kp= (PH2)12* (Pl2)12PHl= (0.2)12* (0.2)120.6

8.31*300*2.3*log (13)=2735J/mol

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Vishal Baghel

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π = i * c * R * T = 2 * 0 . 8 3 * 3 0 0 6 0 * 1 0 3 = 0 . 0 0 4 1 5 b a r

= 415 Pa

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Vishal Baghel

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Vapourisation of H2O, H2O (l)H2O (g)

Mole of H2O= 3618=2mol

ΔE=ΔHΔnRT

=41.11*8.31*3731000=38kJ/mole

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Vishal Baghel

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Water has only two lone pair and XeF4 has two lone pair electron in opposite plane of the central atom.

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Vishal Baghel

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After removal A = 4  (12*2)=3

After removal B = 4 – 1 = 4 (only two atoms are removed)

Final formula of the compound = A3B4

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Vishal Baghel

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 CH4+2O2CO2+2H2O

Mole 1001620832

6.256.5 (HereO2isthelimitingreagent)

Hence mole of CO2 formed = 6.52

And wt of CO2  in gm = 6.52*44=143g

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Vishal Baghel

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Vitamin B12 is not water soluble chemical.

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