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New answer posted

9 months ago

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A
alok kumar singh

Contributor-Level 10

This is a Long Answer Type Questions as classified in NCERT Exemplar

A contrast is drawn in thermodynamics between extensive and intense qualities. An extensive property is one whose value is proportional to the amount or size of matter in the system. Extensive properties include mass, volume, internal energy, enthalpy, and heat capacity, to name a few.

Properties that are independent of the amount or size of matter present are known.

As though they were intensive properties Temperature, density, and pressure, for example, are intense properties. A molar property? m, is the value of an extensive property of the system for 1 mol of the sub

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New answer posted

9 months ago

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alok kumar singh

Contributor-Level 10

Resonating structures of phenoxide are-

In structure I and V negative charge is on E.N. Oxygen, in other cases, it is on Less E.N Carbon hence they contribute less towards stability. And the negative charge is localized.

Resonating structures of carboxylic acid-

Both the structures have –ve charge on oxygen and electron are delocalised too hence, the carboxylic acid is more stable and acidic than phenol.

 

 

New answer posted

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alok kumar singh

Contributor-Level 10

Kindly go through the solution:

 

 

New answer posted

9 months ago

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A
alok kumar singh

Contributor-Level 10

1. Cyclohexanone forms cyanohydrin in good yield because the ketonic group has very less steric hindrance at both the ortho position but 2,2,6 tri methyl cyclohexanone have high steric hindrance which reduces the attack from CN nucleophile.

2. Only one Amino group is involved in the resonance structure of semicarbazide hence e- density on NH2 group decreases & it can't act as a nucleophile. But another NH2 group can attack as a nucleophile to form semicarbazones.
3. It is the reversible reaction hence if we don't remove the water or ester the reaction may proceed in backward direction, for that It is essential the water or

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9 months ago

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alok kumar singh

Contributor-Level 10

1. When 1- phenyl ethane is oxidized with a strong oxidizing agent like KMnO4, it forms a benzoic acid ion.

2. When phthalic acid is treated with SoCl2 it chlorinates both carboxyl group to form ptthaloyl chloride.
3. When benzaldehyde is treated with semicarbazide to form benzaldehyde semicarbazone.

4. When benzene is mixed with benzoyl chloride in presence of Anhyd.AlCl3 to give benzophenone.

5. When 4-oxocyclohexanecarbeldehyde is treated with tollens reagent it gets oxidized to carboxylate anion  as it is aldehyde it reduces tollens reagent.

6. When 2-formyl benzoic acid is treated with NaCN it produces 2-[1-hydroxycyanom

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New answer posted

9 months ago

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Payal Gupta

Contributor-Level 10

This is a assertion and reason answer type question as classified in NCERT Exemplar

(i) Statements A and R both are correct and R is the correct explanation of A. Since, metals like Pd and Pt adsorbs a large volume of hydrogen, hence, these are used as a storage media for it. 

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New answer posted

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P
Payal Gupta

Contributor-Level 10

This is a assertion and reason answer type question as classified in NCERT Exemplar

(i) Statements A and R both are correct and R is the correct explanation of A.

MCl2+Na2CO3→ MCO3+2NaCl

MSO4+Na2CO3→MCO3+Na2SO4

New answer posted

9 months ago

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alok kumar singh

Contributor-Level 10

1. Acetylation refers to the process of introducing an acetyl group (resulting in an acetoxy group) into a compound, namely the substitution of an acetyl group for an active hydrogen atom. A reaction involving the replacement of the hydrogen atom of a hydroxyl group with an acetyl group (CH3CO) yields a specific ester, the acetate. Acetic anhydride is commonly used as an acetylating agent reacting with free hydroxyl groups., this reaction is usually carried out in the presence of base like pyridine.

2. Aldeydes having no α-H undergo the disproportion reaction in the presence of Strong alkali, it is a chemical reacti

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