Chemistry

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alok kumar singh

Contributor-Level 10

2. Extraction of chlorine from brine is an oxidation method. The reactions involved are:

2Cl+ 2H2O → 2OH+ H2 + Cl2

For this reaction, the value of ΔG°=+422 kJ, which is positive. Using the formula Δ=−nE°F, we get a negative value of  =−2.2 V.

Since,  =−2.2 V, it would naturally require an external voltage greater than 2.2 V for the reaction to occur.

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Payal Gupta

Contributor-Level 10

24. Option (iii) (C) and (D) is correct since Iodine is a non-polar molecular solid which acts as an insulator while H2O is a hydrogen bonded molecular solid which also acts as an insulator. Whereas Mg is a metal and acts as a conductor in solid and in its molten state and TiO is also an ionic solid which acts as an insulator in solid state but acts as a conductor in molten and in aqueous solutions. 

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New answer posted

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alok kumar singh

Contributor-Level 10

1. Ans:

(a). According to Ellingham diagram, the reaction of CO2 is more feasible at temperatures lower than 710 K and thus it is a better reducing agent below 710 K.

While the reaction of CO is more feasible at temperatures higher than 710 K and thus it is a better reducing agent at above 710 K.

 

(b). According to the Ellingham diagram, the more negative the Gibbs free energy of a particular reaction the more feasible it is to carry out. Since the oxides are easier to reduce, sulfide ores are converted into oxides before reduction.

 

(c). To extract copper,

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Payal Gupta

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23. Option (iii) Diamond  is correct since in diamond, the carbon atoms are held together by strong covalent bonds. It is a giant molecule. Thus, it is a solid network.

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Payal Gupta

Contributor-Level 10

22. Option (i) London forces is correct since iodine molecules are nonpolar  and covalent in nature. These molecules are found to be electrically symmetrical and have no dipole moment. The molecules in a crystal lattice of iodine are thus attracted together by weak London forces.

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Payal Gupta

Contributor-Level 10

21. Option (ii) a regular arrangement of constituent particles observed over a long distance in the crystal lattice is correct since the regularity of the crystalline lattice creates local environments that are the same and hence crystals exhibit sharp melting point.

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Payal Gupta

Contributor-Level 10

20.  (iv) They are anisotropic in nature since amorphous solid shows isotropic properties as they exhibit same values of the properties like refractive index, electrical resistance when measured along different directions.

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Payal Gupta

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19. Option (i) Same in all directions is correct since quartz glass is an amorphous solid showing isotropic properties and hence exhibits the same values of refractive index when measured along different directions.

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Payal Gupta

Contributor-Level 10

18. Option (iv) is correct since in antiferromagnetic substances the domains  are oppositely oriented and hence they cancel out each other's magnetic moments. 

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