Chemistry

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alok kumar singh

Contributor-Level 10

13. Vapor phase refining or Van Arkel's method is used for refining Zr and Ti.

Vapor refining or vapor phase process: The metal is collected in the form of volatile compound that decomposes to pure metal.

Van Arkel method: This method is useful for removing all Oxygen and nitrogen present in the form of impurity in metals like Zr and Ti. The crude metal is heated in an empty vessel with a small amount of iodine. The metal iodine being more covalent volatilises. Impure Zr reacts with iodine to form zirconium tera iodide. 

 

The following reaction occurs Zr + 2I2? ZrI4 The metal iodide is decomposed on

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Payal Gupta

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33. Option (ii) neutral is correct since p-type semiconductor mainly contains positively charged carriers ( holes ) which are able to move freely. It is still considered to be neutral as the fixed acceptor atoms having accepted electrons are negative. 

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alok kumar singh

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12. Sulfide ore of copper contains some types of impurities. Sulfide ores are not reduced easily, but oxide ores are easily reduced. It is necessary to make sulfide ores free from volatile impurities. This can be performed by a roasting method. In this moisture escape and impurities like sulfur, phosphorus, arsenic are oxidized to their volatile oxides. It is performed in a reverberatory furnace. After this process the mass becomes porous.

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Payal Gupta

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32. Option (ii) equal number of cations and anions are missing from the lattice is correct since Schottky defect in crystals occurs when equal numbers of cations and anions are missing from the lattice.

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alok kumar singh

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10. Sulfide ores are not reduced easily, but oxide ores are easily reduced. Sulfide ore of copper contains some types of impurities. This can cause by-product formation and degrade our final product. Iron oxide is present as a key impurity of concern in sulfide ore of copper. During the roasting process the temperature in the furnace is near about 1200°C. During such high temperatures iron oxide which is gangue (impurity) in ore forms slag. Slag is insoluble in molten metal and being lighter floats over the surface of molten metal. Here silica is used as flux.

FeO + SiO2 →FeSiO3 

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Payal Gupta

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31. Option (i) Frenkel defect is correct since it is a type of defect in which an atom is dislocated from its lattice position to an interstitial site. 

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Payal Gupta

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30. Option (iv) ionic solid is correct since in graphite each atom is linked to the other through a covalent bond and hence it is a covalent solid and cannot fall under the category of ionic solid. 

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Payal Gupta

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29. Option (iii) electron is correct since lattice sites can only be occupied by electrons when there is imperfection in a solid and do not occur in pure crystals. Hence, the lattice site in a pure crystal cannot be occupied by electrons.

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Payal Gupta

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28. Option (iv) CrO2 is correct since it shows electrical conductivity similar to the metals. 

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Payal Gupta

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27. Option (iii) TiO3  is correct since certain metal oxides such as VO, VO2, VO3and TiO3  show either metallic or insulating properties depending upon the temperature. 

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