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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Due to the resonance stabilisation of the benzyl ring, compound (B) would conduct the SN1 reaction faster than compound (A). The carbocation C6H5CH2Cl+  is very stable when the -Cl from the ring is cleaved, and it is driven to carry out the SN1 reaction.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Phenol will not react with HCl in the presence of ZnCl2. This is owing to the presence of partial double bond properties between the benzene ring and O, which will result in resonance between the benzene ring and the OH -  group. As a result, no aryl halide will be made.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Nucleophilic substitutions occur when haloalkanes react with aqueous KOH. The tertiary halide 2-Bromo-2-methylpropane will react with aq. KOH the easiest of the compounds because the initial step involves cleavage of the alkyl and halide groups, resulting in the production of the extremely stable carbocation.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Methylenecyclohexane and 1-methylcyclohex-1-ene are two chemicals that can produce 1-chloro-1-methylcyclohexane.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The alkane C5H12 is a hydrocarbon with a molecular mass of 72gmol?1. On photo-chlorination, the tert-isomer of pentane yields a single monochloro derivative and two dichloro derivatives. The following is the structure of the alkane and its chloride derivatives.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The IUPAC name for this compound is 1-Bromo-2,2-dimethylpropane

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Because both methyl groups and chlorine atoms are symmetrically positioned at para-positions in compound (II), these molecules fit better in the crystal lattice than other isomers, and hence have the greatest melting point.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The addition reaction of the alkene produces two products, as indicated below.

CH3−CH2−CH=CH−CH3 + HCl→ A + B

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

When an arene is treated with Cl2 in the presence of FeCl3, the electrophilic addition reaction chlorinates the arene to produce aryl chloride. As a result, the chemical provided is C6H5-CH3, often known as toluene. o-chlorotoluene and p-chlorotoluene are the results of electrophilic substitution chlorination.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

(i) Because the rate of reaction of compound 'A' with aqueous KOH is solely dependent on the concentration of 'A, ' the reaction mechanism is SN1and 'A' is 2-Bromo-2-methylpropane (tertiary bromide).

'B', on the other hand, is an isomer of 'A' and is optically active. As a result, 'B' has to be 2-Bromobutane. Because the rate of reaction of 'B' with aqueous KOH is determined by its concentration, the reaction mechanism is SN2.

(ii) Compound 'B' will have an inverted conformation as a result of the SN2 reaction, resulting in an inverted product.

Structure 'A' i

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