The S-block Elements

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V
Vishal Baghel

Contributor-Level 10

Li+ has the largest size in aqueous solution due to its high polarizing power.

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A
alok kumar singh

Contributor-Level 10

It does not contains 2nd most abundant element by weight in earth crust because that is Si Calgon -> Na2 [Na4 (PO3)6]

W a t e r s o l u b l e 2 N a + [ N a 4 ( P O 3 ) 6 ] 2

C a 2 + 2 N a + [ N a 2 C a ( P O 3 ) 6 ] 2

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Vishal Baghel

Contributor-Level 10

Baking soda = NaHCO3

Washing soda = Na2CO3. 10H2O

Caustic soda = NaOH

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alok kumar singh

Contributor-Level 10

Due to high crystallity Be has the highest M.P.

Be = 1560 K

Mg = 925 K

Ca = 1120 K

Sr = 1062 K

 

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alok kumar singh

Contributor-Level 10

Baking soda = NaHCO3

Washing soda = Na2CO3. 10H2O

Caustic soda = NaOH

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2 weeks ago

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R
Raj Pandey

Contributor-Level 9

B2H6 has 4 2 c -2e bonds and 2 3c-2e bonds.

Bridging (B-H) bonds have more value of bond- length then terminal (B – H) bonds

Bridging bonds are in one plane, but terminal bonds are in perpendicular plane.

Due to presence of (3c-2e) bonds, it behaves as electrons deficient and prone to get attached by  lewis  base.

3 N a B H 4 + 4 B F 3 Δ 3 N a B F 4 + 2 B 2 H 6

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Raj Pandey

Contributor-Level 9

Due to higher extent of polarization by Li+ and Mg2+, LiCl and Mgcl2 have covalent character. Therefore they are soluble in ethanol.

 Due to very high value of lattice energy, LiF is having very less solubility in water.

 

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Vishal Baghel

Contributor-Level 10

The blue color of the solution is due to the ammoniated electron which absorbs energy in infrared region of light

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Vishal Baghel

Contributor-Level 10

Thermal stability of compound is directly proportional to large anion of s-block elements:

T.S ∝ 1/ (PP of cation)

And p.p. ∝ charge ∝ 1/size, So, [T.S. ∝ size ∝ 1/ (charge)]

So, Sr [NO? ]? is highly stable

But Mg (NO? )? ⇒ poor

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