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New answer posted

11 months ago

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V
Vishal Baghel

Contributor-Level 10

(b) Is the most stable since it is a tertiary carbocation.

New answer posted

11 months ago

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V
Vishal Baghel

Contributor-Level 10

(b) Iron (III) hexacyanidoferrate (II) (or ferriferrocyanide) Fe4 [Fe (CN)6]is the correct answer.

New answer posted

11 months ago

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A
alok kumar singh

Contributor-Level 10

11.26 

The acidic nature of phenol can be represented by the following two reactions:-

(a) Phenols react with sodium to give sodium phenoxide, liberating H2.

(b) Phenols react with sodium hydroxide to give sodium phenoxide and water as a by-product.

The acidity of phenol is more than that of ethanol. This is because phenol after losing a proton becomes phenoxide ion which undergoes resonance and is stabilized whereas ethoxide ion does not.

The resonating structures of phenoxide ion are shown as below:

The lone pair of electrons on oxygen delocalizes into the benzene (mesomeric effect) which reduces the electron density in the O-H bon

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New question posted

11 months ago

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New answer posted

11 months ago

0 Follower 8 Views

V
Vishal Baghel

Contributor-Level 10

Mass of the compound = 0.468 g
Mass of barium sulphate= 0.668 g

% of sulphur = 

                     

New answer posted

11 months ago

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V
Vishal Baghel

Contributor-Level 10

Mass of the compound = 0.3780 g
Mass of silver chloride = 0.5740 g

% of chlorine =

New answer posted

11 months ago

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V
Vishal Baghel

Contributor-Level 10

Step I: Calculation of volume of unused acid i.e. V2 =?

V1 = Volume of NAOH solution required = 60 cm3 

N1 = Normality of NaOH solution = ½ N

N2 = Normality of H2SO4 = 1N

Applying N1V1 = N2V2

½ N x 60 cm3 = 1N x V2

Or V2 = 30 cm3

Step II: calculation of volume of acid used

Volume of acid added = 50 cm3

Volume of unused acid = 30 cm3

Volume of acid used = 50 – 30 = 20 cm3

Step III: Calculation of % of nitrogen

Mass of compound = 0.50 g

Volume of acid used = 20 cm3

Normality of acid used = 1 N

% of nitrogen = (1.4 x 20 x 1) / 0.50 = 56%

New answer posted

11 months ago

0 Follower 79 Views

A
alok kumar singh

Contributor-Level 10

11.25

1-phenylethanol from a suitable alkene

The addition of water takes place according to Markovnikov rule. The alkene taken is styrene. And According to the rule, the positive charge i.e. H+ goes to the carbon of the double bond which has more number of hydrogens and the negative part i.e. OH- goes to the carbon that has less number of hydrogens. Therefore resulting the final product as 1-phenyl ethanol.

 

2. In the above conversion, NaOH gets dissociated into Na+ and OH-and Na+ then combines with Cl of chloromethylcyclohexane forming NaCl and thus the final product Cyclohexylmethanol is obtained.

 

3. In this conversion also,

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New answer posted

11 months ago

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V
Vishal Baghel

Contributor-Level 10

Step 1: Calculation of mass of CO2 produced

Mass of compound = 0.20 g

% of carbon = 69%

i.e. 12/44 x  = Mass of Carbondioxide formed / Mass of Compound = 69/100

Therefore, mass of CO2formed = (69 x 44 x 0.20) / (12 x 100) = 0.506 g

Step 2: Calculation of mass of H2O produced

Mass of compound = 0.20 g

% of hydrogen = 4.8%

i.e. 2/18 x Mass of Water Formed/Mass of Compound = 4.8/100

Therefore, mass of H2O formed = 4.8*18*0.20/2*100 = 0.0864 g

New answer posted

11 months ago

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A
alok kumar singh

Contributor-Level 10

11.24

The reaction given below is:

Benzene reacts with concern. H2SO4 and undergoes the following mechanism:-

Step 1: The equilibrium produces SO3 in concentrated H2SO4, as shown below:

Step 2: SO3 is the electrophile which reacts with benzene to form arenium ion, as shown below:

Step 3: A proton is removed from the arenium ion to form benzenesulfonate ion.

Step 4: The benzenesulfonate ion accepts a proton to become benzene-sulphonic acid, as shown below:

Step 5: The benzene sulphonic acid then reacts with NaOH to give phenol as the final product, as shown below:

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