Class 11th

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alok kumar singh

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

SO3 acts as an electrophile as in this, three highly electronegative oxygen atoms are attached to the sulphur atom which makes it electron deficient. It can be shown by resonance that it gets positive charge and acts as an electrophile.

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alok kumar singh

Contributor-Level 10

26. (b)CH3 -CH2 -CH (Br)-CH2 -CH2 -CH2 -COOH 

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alok kumar singh

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26. CH3 -CH2 -CH2 -CH2 -CH2 -CH2 -CH2Br 

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alok kumar singh

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18. In this structure  i.e.,   3-nitrocyclohex-l-en (Carbon atoms of the ring are numbered in such a way that double bonded carbon gets the lowest number followed by the nitro group -NO2.    

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alok kumar singh

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24. In this structure i.e., 3-ethyl, 4-methylhept-5-en-2-one. (the longest carbon  chain is selected in such a way that the functional group > C = O gets the lowest possible locant.

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alok kumar singh

Contributor-Level 10

23. Whenever an organic compound contains both N and S, then on fusion with Na metal compound gives NaSCN or NaCN and Na2S depending on the quantity of Na metal. If  Na metal is less, then only NaSCN is formed. In that case L.E on treating with FeSO4 and H2SO4 gives red colour due to the formation of ferric thiocyanide Fe (SCN)3. In case of NaCN, L.E on treating with FeSO4 and H2SO4gives Prussian blue colour. 

Chemical reactions: Fe2+ →Fe3+ (Oxidation) 

Fe3+ + 3NaSCN →Fe (SCN)3 + 3Na+ 

                  &nb

...more

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alok kumar singh

Contributor-Level 10

22. Four possible carbocations can be obtained from 2- methyl butane  are 

Generally, order of stability follows the order-

1° carbocation < 2 carbocation < 3 carbocation 

Order of increasing stability of the given structures is-

I < IV < II < III.

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alok kumar singh

Contributor-Level 10

21. Triphenylmethyl cation is found to be very much stable as this positive charge on methyl carbon is delocalized in three phenyl rings. In each phenyl ring, positive charge is developed on 2 ortho position and para position, i.e., three resonating structures. Total resonating structures given by triphenylmethyl cation are nine. Hence, it is very stable. These structures can be shown as.

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