Class 12th
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New answer posted
8 months agoContributor-Level 10
We know that,
cos3θ= 4cos3θ - 3cosθ
Letx = cosθ Then θ = cos-1x. We have,
Cos3 (cos-1x) = 4x3-3x
3cos-1x = cos-1 (4x3- 3x)
Hence Proved
New answer posted
8 months agoContributor-Level 10
We know that.
sin 3θ =3 sin θ 4sin3θ (identity).
(E) Let x = sinθ. Then, sin −1x=θ . We have,
Sin3 (sin −1x) = 3x−4x3
3sin −1x =sin-1 (3x−4x3)
Hence proved.
New answer posted
8 months agoContributor-Level 10
Given, Sin−1x=y.
(E) We know that the principal value branch of Sin−1 is
Hence, ≤ y ≤
Option B is correct.
New answer posted
8 months agoContributor-Level 10
Let cos -1 =y Then cos y = = − cos
cos
= cos
= cos
(E) We know that the range of principal value
branch of cos−1 is [0, ] and cos =
Principal value of cos−1 is
New answer posted
8 months agoContributor-Level 10
Let sin−1 =y. Then, sin y=-
We know that the range of principal value branch of sin−1 is
and sin−1
=
Principal value of sin−1
New answer posted
8 months agoContributor-Level 10
4.39 Given, k2 = 4k1, T1 = 293K and T2 = 313K
We know that from the Arrhenius equation, we obtain
On solving, we get,
Ea = 58263.33 J mol-1 or 58.26 kJ mol-1
New answer posted
8 months agoContributor-Level 10
4.38 We know, time t = (2.303/k) * log ( [R]0/ [R])
Where, k- rate constant
[R]0-Initial concentration
[R]-Concentration at time 't'
At 298K, If 10% is completed, then 90% is remaining. t = (2.303/k) * log ( [R]0/0.9 [R]0)
t = (2.303/k) * log (1/0.9) t = 0.1054 / k
At temperature 308K, 25% is completed, 75% is remaining t' = (2.303/k') * log ( [R]0/0.75 [R]0)
t' = (2.303/k') * log (1/0.75) t' = 2.2877 / k'
But, t = t'
0.1054 / k = 2.2877 / k' / k = 2.7296
From Arrhenius equation, we obtain log k2/k1 = (Ea / 2.303 R) * (T2 - T1) / T1T2
Substituting the values,
Ea = 76640.09 J mol-1 or 76.64 kJ mol-1 We know, log k = log A –Ea/RT
Log k =
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