Class 12th

49. Option (i) A (3) B (4) C (2) D (1)

Sapphire is a gemstone containing Co.

Hence, option (A) from column I is matched with option (3) from column II. The Sphalerite single is ZnS.

Hence, option (B) from column I is matched with option (4) from column II. NaCN is also used as a depressant.

Hence, option (C) from column I is matched with option (2) from column II. Al2O3 is also called corundum.

Hence, option (D) from column I is matched with option (1) from column II.

30. (A) Cu (II) is more stable .

Electronic configuration of Cuis [Ar] 3d¹⁰ 4s¹

Cu (I) - [Ar] 3d¹⁰ 4s0

Cu (II)- [Ar] 3d⁹ 4s0

Despite the fact that Cu (I)  has fully filled 3d-orbital but Cu (II) is more stable than Cu (I) due to the greater effective nuclear charge of Cu (II) as nucleus has to hold 17 electrons rather than 18 electrons like in Cu (I).

The equation of the parabola is $y^2=4a^2$ -----------(1)

and that of line is $y=mx$ ------(2)

The Point of intersection of(1)and (2) is given by

$\begin{array}{l}{\left(mx\right)}^2=4ax\\ \Rightarrow m^2{x}^2-4ax=0\\ \Rightarrow x\left(m^{2}x-4a\right)=0\\ \Rightarrow x=0\&x=\frac{4a}{m^2}\end{array}$

For, $x=0,y^2=4a*0\to y=0$ i.e, O(0,0)

For, $x=\frac{4a}{m^2},y^2=4a*\frac{4a}{m^2}\to y=\frac{4a}{m}$ (in first quadrant)

i.e, $A\left(\frac{4a}{m^2},\frac{4a}{m}\right)$

Hence, the required area enclosed by the curve and the lines is

$area(DACO)=area(OCABO)-area(?OAB)$

29.  (B) 26

Positive oxidation states indicate the loss of electrons from the atom. If X is in +3 oxidation state, then three electrons have been removed from it. Find the atomic number of the parent atom, we will add three in the given electronic number. i.e.

X³⁺  (Z = 23)  =  [Ar] 3d⁵

X  =  23 + 3  = 26  

The given equation of the curve is $y=sinx$

$\therefore$ The required area bounded by the curve

$\begin{array}{l}={\displaystyle \underset{0}{\overset{\pi }{\int }}y}dx+{\displaystyle \underset{\pi }{\overset{2\pi }{\int }}y}dx\\ ={\displaystyle \underset{0}{\overset{\pi }{\int }}sinxdx+{\displaystyle \underset{\pi }{\overset{2\pi }{\int }}sinxdx}}\\ =\left|{\left[-cosx\right]}_0^{\pi }\right|+\left|{\left[-cosx\right]}_0^{\pi }\right|\\ =|-\left[cosx-cos\theta \right]|+|-\left[cos2\pi -cos\pi \right]|\\ =|-\left[-1-1\right]|+|-\left[1+1\right]|\\ =\left|2\right|+|-2|=2+2=4uni{t}^2\end{array}$

Given equation of lines is $y=|x+3|$ -------(1)

The point (x,y)satisfying (1)are

Hence plotting the above in graph we get     

Now, ${\displaystyle \underset{-6}{\overset{0}{\int }}|x+3|dx=}{\displaystyle \underset{-6}{\overset{-3}{\int }}|x+3|dx+{\displaystyle \underset{-3}{\overset{0}{\int }}|x+3|dx}}$

We know that, $\begin{array}{l}{\displaystyle \underset{-6}{\overset{0}{\int }}|x+3|dx=}{\displaystyle \underset{-6}{\overset{-3}{\int }}|x+3|dx+{\displaystyle \underset{-3}{\overset{0}{\int }}|x+3|dx}}\\ y=|x+3|=\left\{\begin{array}{l}x+3,if,x+3\ge 0\Rightarrow x\ge -3\\ -\left(x+3\right),if,x+3\angle 0\Rightarrow x\angle -3\end{array}\right\}\end{array}$

So, ${\displaystyle \underset{-6}{\overset{0}{\int }}|x+3|dx=}{\displaystyle \underset{-6}{\overset{-3}{\int }}-\left(x+3\right)dx+}{\displaystyle \underset{-3}{\overset{0}{\int }}\left(x+3\right)dx}$

$\begin{array}{l}=-{\left[\frac{x^2}{2}+3x\right]}_{-6}^{-3}+{\left[\frac{x^2}{2}+3x\right]}_{-3}^0\\ =-\left\{\left[\frac{{\left(-3\right)}^2}{2}+3\left(-3\right)\right]-\left[\frac{{\left(-6\right)}^2}{2}+3\left(-6\right)\right]\right\}+\left\{\left[\frac{0^2}{2}+3*0\right]-\left[\frac{{\left(-3\right)}^2}{2}+3*\left(-3\right)\right]\right\}\\ =-\left\{\frac{9}{2}-9-\frac{36}{2}+18\right\}+\left\{-\frac{9}{2}+9\right\}\\ =-\frac{9}{2}+9+18-18-\frac{9}{2}+9\\ =9uni{t}^2\end{array}$

Given curve is $y=4x^2\Rightarrow x^2=\frac{1}{4}y$ - (1)

$x=0$  i.e, y-axis and y=4 and y=1

Hence, the required area in Ist quadrant i.e, area ABCD = ${\displaystyle \underset{y=1}{\overset{y=4}{\int }}xdy}$

48. Correct code (i) A (4) B (2) C (3) D (1)

The cyanide process is used in the extraction of Au.

Hence, option (A) from column I is matched with option (4) from column II. Froth floatation process is used in the dressing of ZnS.

Hence, option (B) from column I is matched with option (2) from column II. Electrolytic reduction is used in the extraction of AI.

Hence, option (C) from column I is matched with option (3) from column II. Zone refining is used to get ultrapure Ge.

Hence, option (D) from column I is matched with option (1) from column II.

The given equation of the curve is $y=x^2$ --------(1)

and that of the line is $y=x$ ---------(2)

Solving eq (1) and (2)for x and y

$\begin{array}{l}x=x^2\\ =x^2-x=0\\ =x\left(x-1\right)=0\\ =x=0\&x=1\end{array}$

Where, $x=0,y=0^2=0$

And when $x=1,y=1^2=1$

$\therefore$ The point of intersection of the parabola $y=x^2$ and the line $y=x$

Is O(0,0) and B (1,1)

Hence, area between the curve and the line is

$area\left(DCAO\right)=area\left(?OAB\right)-area\left(OABO\right)$

$\begin{array}{l}={\displaystyle \underset{0}{\overset{1}{\int }}{y}_{line}}dx-{\displaystyle \underset{0}{\overset{1}{\int }}{y}_{curve}}dx\\ ={\displaystyle \underset{0}{\overset{1}{\int }}xdx-{\displaystyle \underset{0}{\overset{1}{\int }}{x}^{2}dx}}\\ ={\left[\frac{x^2}{2}\right]}_0^1-{\left[\frac{x^3}{3}\right]}_0^1\end{array}$

$\begin{array}{l}=\frac{1}{2}-\frac{1}{3}\\ =\frac{3-2}{6}=\frac{1}{6}uni{t}^2\end{array}$

(i) Given of curve is $y=x^2\Rightarrow x^2=y$ and the equation are $x=1\&x=2.$

$\therefore$ Area enclosed

$\begin{array}{l}={\displaystyle \underset{x=1}{\overset{x=2}{\int }}y}dx\\ ={\displaystyle \underset{1}{\overset{2}{\int }}{x}^2}dx\\ ={\left[\frac{x^3}{3}\right]}_1^2=\frac{2^3}{3}-\frac{1^3}{3}\\ =\frac{8-1}{3}=\frac{7}{3}uni{t}^2\end{array}$

(ii) Given equation of curve is $y=x^4$ and the lines are $x=1\&x=5$

So, area enclosed

$\begin{array}{l}={\displaystyle \underset{1}{\overset{5}{\int }}y}dx\\ ={\displaystyle \underset{1}{\overset{5}{\int }}{x}^4}dx\\ ={\left[\frac{x^5}{5}\right]}_1^5=\left(\frac{5^5-1^5}{5}\right)\\ =\frac{\left(3125-1\right)}{5}\\ =\frac{3124}{5}=624.8uni{t}^2\end{array}$