Class 12th

33.  (A) Mn₂O₇

2KMnO₄ +  2H₂SO₄ (conc.) → Mn₂O₇ +    2KHSO₄ + H₂O

Manganese heptoxide is an acid anhydride of permanganic acid ( HMnO₄). It is a dangerous oxidiser, volatile and highly reactive liquid.

Given that equation of

curve $y=x^2$

line $y=\left|x\right|=\left\{x,ifx\ge 0\&-x,ifx\angle 0\right\}$

Since the line passes through A&B in Ist and IInd quadrants

the equation must satisfy

$\Rightarrow y=x^2$

$\Rightarrow x=x^2$ for Ist quadrant and

$\Rightarrow -x=x^2$ for IInd t quadrant

So, $\Rightarrow x^2-x=0$ and $x^2+x=0$

$\Rightarrow x\left(x-1\right)=0$ and $x\left(x+1\right)=0$

$\Rightarrow x=0,1$ $x=0,-1$

$x=0,y=0$

$x=1,y=1$ i.e, A has coordinate (1,1)

$x=-1,y=1$ i.e, B has coordinate (1,1)

Now, area of AODA = area (AOM)-area (ADOM)

$={\displaystyle \underset{0}{\overset{1}{\int }}{y}_{line}dx-{\displaystyle \underset{0}{\overset{1}{\int }}{y}_{curve}dx}}$

$={\displaystyle \underset{0}{\overset{1}{\int }}xdx-{\displaystyle \underset{0}{\overset{1}{\int }}{x}^2}dx={\left[\frac{x^2}{2}\right]}_0^1-}{\left[\frac{a^3}{3}\right]}_0^1$

$=\frac{1}{2}-\frac{1}{3}=\frac{3-2}{6}=\frac{1}{6}unit{s}^2$

$\therefore$ The required area of the region bounded by curve $y=x^2$ and line $y=\left|x\right|$ is $\frac{1}{6}+\frac{1}{6}=\frac{2}{6}=$$\frac{\mathrm{}}{}$$\frac{1}{3}unit{s}^2$

Given equation of the curve is $\left|x\right|+\left|y\right|=1$ , which can be break down into each quadrant .

For Ist quadrant,  $\left|x\right|=x,\left|y\right|=y$

i.e.,  $x+y=1$ - (1)

Similarly for IInd, IIIRd nad IVth quadrant

$-x+y=1$ - (2)

$-x-y=1$ - (3)

$x-y=1$ - (4)

We draw the above focus lines on a graph and find the area enclosed which is a square.

$\therefore$ Required area $\left(?ABCD\right)=4*area\left(?AOB\right)$ .

$\begin{array}{l}=4*{\displaystyle \underset{0}{\overset{1}{\int }}y}dx\\ =4{\displaystyle \underset{0}{\overset{1}{\int }}\left(-x\right)}dx\\ =4{\left[x-\frac{x^2}{2}\right]}_0^1\\ =4\left[1-\frac{1}{2}\right]\\ =4*\frac{1}{2}\\ =2uni{t}^2\end{array}$

The given equation of the parabola is $x^2=y$ ---------(1)

and that the line is $y=x+2$ --------------(2)

Solving (1) and (2) for x and y

$\begin{array}{l}{x}^2=x+2\\ \to x^2-x-2=0\\ =x^2+x-2x-2=0\\ =x\left(x+1\right)-2\left(x+1\right)=0\\ =\left(x+1\right)\left(x-2\right)=0\\ =x=-1\&x=2\end{array}$

When $x=-1,y={\left(-1\right)}^2=1$

And $x=2,y=2^2=4$

$\therefore$ The point of intersection of the parabola and the lines $A(-1,1)\&B(2,4)$

Hence the required area enclosed region is $ea(AOBA)=area(DABCD)-area(DAOBCD)$

$\begin{array}{l}={\displaystyle \underset{-1}{\overset{2}{\int }}{y}_{line}dx-}{\displaystyle \underset{-1}{\overset{2}{\int }}{y}_{curve}dx}\\ ={\displaystyle \underset{-1}{\overset{2}{\int }}\left(x+2\right)dx}-{\displaystyle \underset{-1}{\overset{2}{\int }}{x}^{2}dx}\\ ={\left[\frac{x^2}{2}2x\right]}_{-1}^2-{\left[\frac{x^3}{3}\right]}_{-1}^2\end{array}$

$\begin{array}{l}=\left[\left(\frac{2^2}{2}2.2\right)-\left(\frac{{\left(-1\right)}^2}{2}+2\left(-1\right)\right)\right]-\left[\frac{2^3}{3}-\frac{{\left(-1\right)}^3}{3}\right]\\ =\left[2+4-\frac{1}{2}+2\right]-\left[\frac{8+1}{3}\right]=\frac{15}{2}-3=\frac{9}{2}uni{t}^2\\ \end{array}$

32.  (B) CuF₂

(A) Ag₂SO₄  (Ag⁺ )→ 5d¹⁰6s⁰

(B) CuF₂  (Cu²⁺ )→ 3d⁹4s⁰

(C) ZnF₂  (Zn²⁺)→ 3d¹⁰4s⁰

(D) Cu₂Cl₂  (Cu⁺)→ 3d¹⁰6s⁰

Unpaired electrons present in any compound impart colour to the salt of transition metal. Only CuF₂ has unpaired electrons in its 3d orbital that's why it is white coloured in its solid-state while rest of the salts are colourless.

The Given equation of the ellipse is $\frac{x^2}{a^2}+\frac{y^2}{b^2}=1$

And the equation of the line in $\frac{x}{a}+\frac{y}{b}=1$

With x and y intersept a and b

So, required area of the enclosed region is

$area(BCAB)=area(OBCAO)-area(?OBA)$

Given equation of the ellipse is $\frac{x^2}{9}+\frac{y^2}{4}=1$ Which as major axis aling x- axis and that of the line is $\frac{x}{3}+\frac{y}{2}=1$ which has x and y intercepts at 3 and 2respectively.

Required area of enclosed region is area $area(BCAB)=area(OBAO)?area(ABOA)$

31.  (D) Cu

Density is mass by volume. As we move from left to right for a long period, the atomic radii decrease. Hence, volume decreases. Also, an increase in atomic masses is observed. 

So overall the density increases out of the above option from iron to copper, copper will have the highest density.

The given equation of parabola is $4y=3x^2\Rightarrow x^2=\frac{4}{3}y$ ------------(1)

And the line is $2y=3x+12\Rightarrow y=\frac{3}{2}x+6$ ----------------------(2)

Solving (1) and (2) for x and y,

$\begin{array}{l}{x}^2=\frac{4}{3}\left(\frac{3}{2}x+6\right)=2x+8\\ \Rightarrow x^2-2x-8=0\\ \Rightarrow x^2-4x+2x-8=0\\ \Rightarrow x\left(x-4\right)+2\left(x-4\right)=0\\ \Rightarrow \left(x-4\right)\left(x+2\right)=0\\ \Rightarrow x=4\&x=-2\end{array}$

At, $x=4,y=\frac{3}{2}*4+6=6+6=12$

And $x=-2,y=\frac{3}{2}*\left(-1\right)+6=-3+6=3$

Thus, the point of intersection of (1)&(2)are $A(4,12)\&B(-2,3)$

$\therefore$ Area of the enclosed region (BOAB)

=area (CBAD) – area (OADC)

$\begin{array}{l}={\displaystyle \underset{-2}{\overset{4}{\int }}{y}_{line}dx-}{\displaystyle \underset{-2}{\overset{4}{\int }}{y}_{curve}dx}\\ ={\displaystyle \underset{-2}{\overset{4}{\int }}\left(\frac{3}{2}x+6\right)dx-{\displaystyle \underset{-2}{\overset{4}{\int }}\frac{3x^2}{4}dx}}\\ ={\left[\frac{3}{2}\frac{x^2}{2}+6x\right]}_{-2}^4-{\left[\frac{3}{4}*\frac{x^3}{3}\right]}_{-2}^4\\ =\left[\left(\frac{3}{4}*4^2+6*4\right)-\left(\frac{3}{4}{\left(-2\right)}^2+6*\left(-2\right)\right)\right]-\frac{1}{4}\left[4^3-{\left(-2\right)}^3\right]\\ =\left[12+24-3+12\right]-\frac{1}{4}\left[64+8\right]\\ =45-18=27uni{t}^2\end{array}$