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Ncert Solutions Chemistry Class 11th

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3 weeks ago

Ncert Solutions Chemistry Class 11th Thermodynamics

2.2g of nitrous oxide (N₂O) gas is cooled at a constant pressure of 1 atm from 310 K to 270 K causing the compression of the gas from 217.1mL to 167.75mL. The change in thermal energy of the process, $Δ U$ is '-x' J. The value of 'x' is________. [Nearest Integer]

(Given : atomic mass of N = 14 g mol^-1 and of O = 16 g mol^-1.

Molar heat capacity of N₂O is 100 J K^-1 mol^-1)

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Vishal Baghel

Contributor-Level 10

Moles of N₂O= $\frac{2.2}{44} = \frac{1}{20}$

$Δ H = n C_{p} Δ T = \frac{1}{20} * 100 (- 40) = - 200 J$

$Δ U = q_{p} + w$

$w = - P_{e x t} . Δ V$

$w = - 1 \frac{(167.75 - 217.1)}{1000} * 101.3 J = + 5 J$

$Δ U = - 200 + 5 = 195 J$

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Ncert Solutions Chemistry Class 11th Class 11th

A box contains 0.90g of liquid water in equilibrium with water vapour at 27°C. The equilibrium vapour pressure of water at 27°C is 32.0 Torr. When the volume of the box is increased, some of the liquid water evaporates to maintain the equilibrium pressure. If all the liquid water evaporates, then the volume of the box must be________ litre. [Nearest Integer]

(Given : R = 0.082 L atm K^-1 mole^-1)

(Ignore the volume of the liquid water and assume water vapours behave as an ideal gas.)

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Vishal Baghel

Contributor-Level 10

$\frac{n R T}{P} = \frac{0.90 * 0.0821 * 300}{18 * 32} * 760 = 29.21 ≅ 29$

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Ncert Solutions Chemistry Class 11th Class 11th

A white precipitate was formed when BaCl₂ was added to water extract of an inorganic salt. Further, a gas 'X' with characteristic odour was released when the formed white precipitate was dissolved in dilute HCl. The anion present in the inorganic salt is

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Vishal Baghel

Contributor-Level 10

$B a C l_{2} + S O_{3}^{2 -} \overset{}{\to} \underset{W h i t e}{B a S O_{3}} ↓ \overset{d i l . H C l}{\to} \underset{\begin{array}{l} b u r n i n g s u l p h u r \\ l i k e s m e l l \end{array}}{S O_{2} ↑}$

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Ncert Solutions Chemistry Class 11th Class 11th

50 mL of 0.1 M CH₃COOH is being titrated against 0.1 M NaOH. When 25 mL of NaOH has been added, the pH of the solution will be_________* 10^-². (Nearest integer)

(Given : pKa (CH₃-COOH) = 4.76)

log 2 = 0.30

log 3 = 0.48

log 5 = 0.69

log 7 = 0.84

log 11 = 1.04

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alok kumar singh

Contributor-Level 10

Here, total meq of acetic acid = 50 * 0.1 = 5

And total meq of NaOH = 25 * 0.1 = 2.5

After neutralization process

Meq of left acetic acid = 2.5

And meq of formed CH₃COONa = 2.5

$p H = p K a + l o g_{10} \frac{[S]}{[A]}$

$p H = 4.76 + l o g_{10} \frac{2.5}{2.5} = 4.76 = 476 * 1 0^{- 2}$

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Ncert Solutions Chemistry Class 11th Class 11th

For complete combustion of methanol

$C H_{3} O H (1) + \frac{3}{2} O_{2} (g) \to C O_{2} (g) + 2 H_{2} O (I)$

The amount of heat produced as measured by bomb calorimeter is 726 kJmol^-¹ at 27°C. The enthalpy of combustion for the reaction is -x kJ mol^-¹, where x is_________

(Nearest integer)

(Given : R = 8.3 J K^-¹ mol^-¹).

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