Ncert Solutions Chemistry Class 11th

Choose the correct stability order of group 13 elements in their +1 oxidation state.

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In boron family lower O.S (+1) is more stabilize down the group due to inert pair effect.

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An evacuated glass vessel weights 40.0g when empty, 135.0g when filled with a liquid of density 0.95 g mL^-¹ and 40.5 g when filled with an ideal gas at 0.82 atm at 250 K. The molar mass of the gas in g mo^-¹ is:

(Given: R = 0.082 L atm K^-¹ mol^-¹)

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Wt of liquid = 135 – 40 = 95 gm

Volume of liquid = $\frac{w t .}{d e n s i t y} = \frac{95}{0.95} = 100 m l$

Hence volume of vessel = 100 ml = 0.1 lit from ideal gas equation,

$M = \frac{d R T}{P} = \frac{0.5}{0.1} * \frac{0.0821 * 250}{0.82}$

$∴ M = 125 g / m o l$

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4.0 L of an ideal gas is allowed to expand isothermally into vacuum until the total volume is 20L. The amount of heat absorbed in this expansion is _________L atm.

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For expansion in vacuum, workdone, w = 0

For isothermal process, $Δ U = 0$

According to first law of thermodynamics,

$\begin{array}{l} Δ U = q + w \\ q = 0 \end{array}$

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.2g of nitrous oxide (N₂O) gas is cooled at a constant pressure of 1 atm from 310 K to 270 K causing the compression of the gas from 217.1mL to 167.75mL. The change in thermal energy of the process, $Δ U$ is '-x' J. The value of 'x' is________. [Nearest Integer]

(Given : atomic mass of N = 14 g mol^-1 and of O = 16 g mol^-1.

Molar heat capacity of N₂O is 100 J K^-1 mol^-1)

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Moles of N₂O = $\frac{2.2}{44} = \frac{1}{20}$

$Δ H = n C_{p} Δ T = \frac{1}{20} * 100 (- 40) = - 200 J$

$Δ U = q_{p} + w$

$w = - P_{e x t} . Δ V$

$w = - 1 \frac{(167.75 - 217.1)}{1000} * 101.3 J = + 5 J$

$Δ U = - 200 + 5 = 195 J$

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Given below are two statements:

Statement I : The pentavalent oxide of group-15 element, E₂O₅, is less acidic than trivalent oxide, E₂O₃, of the same element.

Statement II : The acidic character of trivalent oxide of group 15 elements, E₂O₃ decreases down the group.

In light of the above statements, choose most appropriate answer form the options given below:

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Pentavalent oxides of group – 15 elements, E₂O₅ is more acidic than trivalent oxides, E₂O₃ of the same element.

Acidic strength of trivalent oxides decreases down the group as metallic strength increases.

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Nitrogen gas is obtained by thermal decomposition of

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N₂ gas is obtained by thermal decomposition of Ba (N₃)₂ as,

$B a {(N_{3})}_{2} \to_{}^{Δ} B a + 3 N_{2} ↑$

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A white precipitate was formed when BaCl₂ was added to water extract of an inorganic salt. Further, a gas 'X' with characteristic odour was released when the formed white precipitate was dissolved in dilute HCl. The anion present in the inorganic salt is

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$B a C l_{2} + S O_{3}^{2 -} \overset{}{\to} \underset{W h i t e}{B a S O_{3}} ↓ \overset{d i l . H C l}{\to} \underset{\begin{array}{l} b u r n i n g s u l p h u r \\ l i k e s m e l l \end{array}}{S O_{2} ↑}$

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Dihydrogen reacts with CuO to give

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$C u O + H_{2} \to C u + H_{2} O$

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Aqueous solution of which of the following boron compounds will be strongly basic in nature?

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Borax forms basic buffer solution in aqueous medium.

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Amongst baking soda, caustic soda and washing soda, carbonate anion is present

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