Ncert Solutions Chemistry Class 12th

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New answer posted

9 months ago

0 Follower 6 Views

A
alok kumar singh

Contributor-Level 10

This is a Fill in the blanks Type Question as classified in NCERT Exemplar

Ans: Correct option C

In the given graph V is the volume in the Y axis and time is in X axis

Zn + dil.HCl→ZnCl2 + H2

Average rate = 40s

Average rate of reaction = C h a n g e i n C o n c e n t r a t i o n o f H 2 C h a n g e i n t i m e

F i n a l C o n c e n t r a t i o n - I n i t i a l C o n c e n t r a t i o n F i n a l t i m e - I n i t i a l T i m e

Analyzing the graph line where time and volume intersect. 

V 3 - 0 40 - 0

V 3 40

New answer posted

9 months ago

0 Follower 2 Views

A
alok kumar singh

Contributor-Level 10

This is a Fill in the blanks Type Question as classified in NCERT Exemplar

Ans: Correct option D

k = Ae -    E a R T             

From this equation

1 E a

When Activation energy Ea decreases, rate constant k

 

 increases.

Hence, Rate constant increases exponentially with decreasing activation energy and increasing temperature. 

New answer posted

9 months ago

0 Follower 11 Views

A
alok kumar singh

Contributor-Level 10

This is a Fill in the blanks Type Question as classified in NCERT Exemplar

Ans: Correct option A

Arrhenius equation Ae -   E a R T

K = rate constant

A= frequency factor

Ea= Activation Energy

R= gas constant

T= temperature

ln k = lnA - E a R T

When the temperature rises, ln falls.

ln kv/s 1 T , is a negative slope.

ln A is intercepted by k, and its magnitude decreases with time.

Negative slope is obtained.

When compared to the other possibilities, T is increasing over time, which is incorrect.

ln k =  - E a R 1 T  + lnA

 

New answer posted

9 months ago

0 Follower 10 Views

A
alok kumar singh

Contributor-Level 10

This is a Fill in the blanks Type Question as classified in NCERT Exemplar

Ans: Correct option B

Given:  

A (g) → B (g) + C (g) 

pi= Initial pressure

(Time) t = 0

 

A (g) → B (g) + C (g) 

pi        →0atm + 0atm

t, (pi - x)atm

pt = (pi - x)atm + x + x = pi + x

pA = (p- x)

 

The value of x changes when it is substituted.

pA = p- (pt - pi) = 2p- pt

K =  2.303 t log p i 2 p i - p t

 

New answer posted

9 months ago

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P
Payal Gupta

Contributor-Level 10

This is a assertion and reason answer type question as classified in NCERT Exemplar

Because m-nitrochlorobenzene is not a stable molecule, the -NO2 group is a meta-directing group, and the reactions' products include nitro groups at the o- and p- positions.

Correct Answer: Option (iv)

New answer posted

9 months ago

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Payal Gupta

Contributor-Level 10

This is a assertion and reason answer type question as classified in NCERT Exemplar

The SN2 mechanism is demonstrated by the hydrolysis of alkyl halides with inversion of configuration. This is a one-step method that does not need the production of carbocation.

Correct Answer: Option (iii)

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9 months ago

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Payal Gupta

Contributor-Level 10

This is a assertion and reason answer type question as classified in NCERT Exemplar

Due to resonance, a partial double bond character occurs in the bond between the C and Cl atoms in chlorobenzene, and we all know that changing a partial double bond character is more difficult than replacing a single bond as in the C - Cl bond in chloroethane.

Correct Answer: Option (i)

New answer posted

9 months ago

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Payal Gupta

Contributor-Level 10

This is a assertion and reason answer type question as classified in NCERT Exemplar

Oxidising chemicals such as HIO3 oxidise HI to I2 because the presence of HI causes the aryl iodides to revert to arenes in their absence.

Correct Answer: Option (iii)

New answer posted

9 months ago

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Payal Gupta

Contributor-Level 10

This is a assertion and reason answer type question as classified in NCERT Exemplar

Because halogen atoms are ortho and para directing, rather than ring deactivators, further electrophilic substitution occurs at ortho and para locations.

Correct Answer: Option (v)

New answer posted

9 months ago

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P
Payal Gupta

Contributor-Level 10

This is a assertion and reason answer type question as classified in NCERT Exemplar

The nitro group on the ortho and para positions of haloarenes acts as an electron-withdrawing group, making it more reactive to nucleophilic substitution reactions due to the electron deficit.

Correct Answer: Option (i)

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