Chemistry NCERT Exemplar Solutions Class 11th Chapter Thirteen

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Payal Gupta

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It is a Wurtz reaction where alkane is formed.

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Payal Gupta

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The structure of 2-methylbutane is 

2-methylbutane

 

Total number 

Total amount of monochlorinated

Product

% of monochlorinated product

9

9

41.7

2

7.6

35.2

1

5

23.1

 

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Payal Gupta

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Electrophiles

Nucleophiles

(iii), (iv), (v)

(i), (ii), (vi), (vii), (viii)

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Payal Gupta

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In presence of (Ph-CO-O)2it lead to CH3-CH2-CH2Br as the reaction undergo by free radical mechanism

However in absence of (Ph-CO-O)2 the reaction undergo by carbocation intermediate thus lead to give CH3-CHBr-CH3

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Payal Gupta

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The nitro group strongly deactivate the benzene towards the electrophilic substitution reaction due to the -R and -I effect

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Payal Gupta

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Due to the +R effect halogens are ortho and para directing groups.

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Payal Gupta

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The electron donating group increases the reactivity in electrophilic substitution reaction whereas the electron withdrawing group decreases the reactivity in electrophilic substitution.

Thus, the order of reactivity

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Payal Gupta

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Payal Gupta

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The benzene here would undergo Friedel-Crafts alkylation reaction where carbocation is formed as an intermediate, thus secondary carbocation is formed as an intermediate due to its greater stability than that of the primary carbocation.

The final product obtained is 

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