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8 months ago

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Payal Gupta

Contributor-Level 10

5.18. Given, P1 = P2 and V1 = V2

We know that P1V1 = P2V2

Or,                n1RT1 = n2RT2

i.e.,                  n1T1 = n2T2

 Substituting n = w/M, we get

(W1/M1) x T1 = (W2/M2) x T2

(2.9/M1) x (95 + 273) = (0.184/2) x (17 + 273)

M1 = (2.9 x 368 x 2) / (0.184 x 290) = 40 g mol-1

New answer posted

8 months ago

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Payal Gupta

Contributor-Level 10

5.17. No. of moles of CO2 = Given mass of CO2 / Molar mass

                                           = 8.8g / 44g mol-1 = 0.2 mol

Pressure of CO2 = 1 bar

RR = 0.083 bar dm3 K–1 mol–1

T = 273 + 31.1 K = 304.1 K

According to ideal gas equation,

PV = nRT

Therefore, V = nRT/P

                      = (0.2 x 0.083 x 304.1) / 1 bar = 5.048 L

New answer posted

8 months ago

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P
Payal Gupta

Contributor-Level 10

5.16. Radius of the balloon = 10 m

Therefore, volume of the balloon = (4/3)? r3 = (4/3) x (22/7) x (10 m)3

= 4190.5 m3

Volume of He filled at 1.66 bar and 27 °C = 4290.5 m3

To calculate the mass of He,

PV = nRT = (w/M) RT, where M is molar mass of He i.e. 4 g per mole or 4 x 10-3 kg mol-1

=> w =  [ (4 x 10-3 kg mol-1) (1.66 bar) (4190.5 m3)] / [ (0.083 bar dm3 K-1 mol-1) (300K)]

         = 1117.5 kg

Total mass of the balloon along with He = 100 + 1117.5 = 1217.5 kg

Maximum mass of the air that can be displaced by balloon to go up = volume x density

= 4190.5 m3 x 1.2 kg m-3 = 5028.6 kg

...more

New answer posted

8 months ago

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P
Payal Gupta

Contributor-Level 10

5.15. Molar mass of O2 = 32 g/mol

It means, 8 g of O2 has 8/32 mol = 0.25 mol

Molar mass of H2 = 2 g/mol

It means, 4 g of H2 has 4/2 mol = 2 mol

Therefore, total number of moles, n = 2 + 0.25 = 2.25 mol

Given, V = 1dm3, T = 27°C = 300 K, R = 0.083 bar dm3 K-1 mol-1

Applying PV = nRT,

P = nRT / V

   = (2.25) (0.083 bar dm3 K-1 mol-1) (300 K) / (1dm3)

   = 56.025 bar

New answer posted

8 months ago

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P
Payal Gupta

Contributor-Level 10

5.14. Time taken to distribute 1010 wheat grains = 1s

Time taken to distribute Avogadro number of wheat grains = (1s x 6.022 x 1023) / 1010

= 6.022 x 1013 s

= (6.022 x 1013 / 60 x 60 x 24 x 365) year

= 1.9 x 106 years

New answer posted

8 months ago

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P
Payal Gupta

Contributor-Level 10

5.13. Molecular mass of N= 28g
28 g of N2 has No. of molecules = 6.022 x 1023 

1.4 g of N2 has No. of molecules = (6.022 x 1023 x 1.4 g)/28 g= 3.011 x 1022 molecules.
Atomic No. of Nitrogen (N) = 7
1 molecule of N2 has electrons = 7 x 2 = 14
3.011 x 1022 molecules of N2 have electrons= 14 x 3.011 x 1022= 4.215 x1023 electrons.

New answer posted

8 months ago

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P
Payal Gupta

Contributor-Level 10

5.12. Given,

P= 3.32 bar

V= 5 dm3 

n= 4 mol

R= 0.083 bar dm3 K-1 mol-1

PV = nRT

Or T = PV / nR = 3.32 x 5 dm3 / (4.0 mol x 0.083 bar dm3 K-1 mol-1)

         = 50 K

New answer posted

8 months ago

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P
Payal Gupta

Contributor-Level 10

9.56. Dihydrogen is prepared from water by the action of alkali metals like Na and K which is a strong reducing agent.

2Na + 2H2O → 2NaOH + H2

2K + 2H2O → 2KOH + H2

New answer posted

8 months ago

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P
Payal Gupta

Contributor-Level 10

9.55. 1. High heat of combustion.

2. It is pollution free.

New answer posted

8 months ago

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P
Payal Gupta

Contributor-Level 10

9.54. Water which does not produce lathers with soap is known as hard water. Hardness is due to the presence of bicarbonates, sulphates and chlorides of Ca2+ and Mg2+.

On boiling, the bicarbonates of calcium and magnesium decompose to insoluble carbonate which can be removed by filtration.

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