Equilibrium

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4 months ago

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Vishal Baghel

Contributor-Level 10

pH = – log [H+] or log [H+] = – pH = – 3.76 = 4.24
Therefore, [H+] = Antilog 4.24 = 1.738 x 10-4 = 1.74 x 10-4 M

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4 months ago

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Vishal Baghel

Contributor-Level 10

pH = – log [H+] = – log (3.8 x 10-3) = – log 3.8 + 3 = 3 – 0.5798 = 2.4202 = 2.42

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Vishal Baghel

Contributor-Level 10

(a) OH ions can donate an electron pair and act as Lewis base.

(b) F– ions can donate an electron pair and actas Lewis base.

(c) H+ ions can accept an electron pair and act as Lewis acid.

(d) BCl3 can accept an electron pair since Boron atom is electron deficient. It is a Lewis acid.

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Vishal Baghel

Contributor-Level 10

NH3, NH4+ and HCOOH

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Vishal Baghel

Contributor-Level 10

Conjugate bases: F, HSO4 , HCO3.

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Vishal Baghel

Contributor-Level 10

BF3, H+ ions are Lewis acids.

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Vishal Baghel

Contributor-Level 10

An acid-base pair which differs by a proton only is known as conjugate acid-base pair. For example,  HCl, and Cl represents conjugate acid base pair.

The conjugate acid/base for the species HNO2, CN, HClO4F, OH, CO32-, and S2- are NO2, HCN, ClO4, HF, H2O, HCO3and HS.respectively.

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Vishal Baghel

Contributor-Level 10

Kc = [CH4] [H2O] / [CO] [H2]3

3.90 = [CH4]*0.02 / (0.30) (0.10)3

[CH4] = 3.90*0.30* (0.10)3 / 0.02

=5.85*102 M

Thus, the concentration of methane in the mixture is 5.85*102 M.

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Vishal Baghel

Contributor-Level 10

The equilibrium constant expression is

Kc = [O3]2 / [O2]3

2.0*1050 = [O3]2 / (1.6*102)3

[O3]2=2.0*1050* (1.6*102)3

 =8.192*1056

Hence, the equilibrium concentration of ozone is

[O3]= 2.86*1028M

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