General Principles & Processes of Isolating Elemen

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2 months ago

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V
Vishal Baghel

Contributor-Level 10

Calcinations is the decomposition in absence of air, Z n C O 3 Δ Z n O + C O 2

while roasting is the oxidation process, 2 Z n S + 3 O 2 2 Z n O + 2 S O 2

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A
alok kumar singh

Contributor-Level 10

Conductivity;    κ = 1 . 0 7 * 1 0 6 S m 1

Resistance ; R = 0.243    Ω

cell constant ; G* =?

Using ;

κ = G * R      

G * = κ * R          

= 1 . 0 7 * 1 0 6 * 0 . 2 4 3 m 1                

= 2 6 * 1 0 4 m 1              

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Vishal Baghel

Contributor-Level 10

Impurities present in electrolytic refining of blister Cu, removed as anode mud

= Sb, Se, Te, Ag, Au, Pt

Ans. = 6

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R
Raj Pandey

Contributor-Level 9

In electrolytic reduction of Al2O3, cryolite (Na3AlF6) is used to increase conductivity & decrease melting point. Oxidation state of Al in cryolite (Na3AlF6) is (+3).

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Raj Pandey

Contributor-Level 9

HgS, PbS, CuS, Sb2S3, As2S3, & CdS are given sulphides

              CdS, PbS, As2S3 & CuS are soluble in 50% HNO3 but Sb2S3 & HgS are not soluble.

              Ans. = 4

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Vishal Baghel

Contributor-Level 10

Liquation is applicable for the refining of low melting point metals.

In liquation low melting point metal, melt at first and impurities take more time for melting therefore we can separate metal from their impurities.

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Raj Pandey

Contributor-Level 9

In electro-refining, impure metal (blister copper) is used as an anode while precious metal like Au, Pt gets deposited as anode mud.

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Vishal Baghel

Contributor-Level 10

Statement-I is true, because metal reduced by decreasing Δ G in Elligham diagram but statement-II is false, Ellingham diagram is Δ G vs temperature graph has no relation with Δ S .

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A
alok kumar singh

Contributor-Level 10

Sphalerite is the sulphide ore of zinc (ZnS) and copper glance Cu2S is the sulphide ores of copper. Two sulphide ores can be separated by adjusting proportion of oil to water or by using depressant in froth flotation method.

 

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P
Payal Gupta

Contributor-Level 10

Liquation refining process is applicable for the metal having low m.p, but containing impurities have higher m.p.

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