General Principles & Processes of Isolating Elemen

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P
Payal Gupta

Contributor-Level 10

Baryte – BaSO4 [Sulphate based ore]

Galena – PbS

Zinc blende – ZnS

Copper pyrite – CuFeS2

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alok kumar singh

Contributor-Level 10

In Hall Heroult process electrolysis is carried out using carbon anode. The liberated

O2 at anode reacts with anode.

Cathode : A l 3 + ( m e l t ) + 3 e k A l ( l )

Anode : C ( s ) + O 2 ( M e l t ) C O ( g ) + 2 e C ( s ) + 2 O 2 ( M e l t ) C O 2 ( g ) + 4 e

Net Reaction 2Al2O3 + 3C 4 A l + 3 C O 2

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Vishal Baghel

Contributor-Level 10

Sphalarite           ZnS

Calamine            ZnCO3

Galena                PbS

Siderite               FeCO3

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A
alok kumar singh

Contributor-Level 10

CaO – Basic Oxide

SO3 & SiO2 – Acidic oxides

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Vishal Baghel

Contributor-Level 10

Ore                                                   Formula

Siderite                                            FeCO3

Malachite        &n

...more

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Vishal Baghel

Contributor-Level 10

 Ce3+ [Xe]4f15d0

Ce4+ [Xe]4f05d0  (Noble gas configuration)

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Vishal Baghel

Contributor-Level 10

 2SO2 (g)+O2 (g)V2O52SO3 (g)contactprocess

4NH3 (g)+5O2 (g)A (s)Rh (s)4NO (g)+6H2O (g) ostwald's process

N2 (g)+3H2 (g)Fe (s)2NH3 (g)Haber'sprocess

Vegetable oil (l) + H2 Ni (s) vegetable ghee; Hydrogenation

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P
Payal Gupta

Contributor-Level 10

Siderite – FeCO3 (ore of iron)

Calamine – ZnCO3 (ore of zinc)

Malachite – CuCO3.Cu (OH)2 (ore of copper)

Cryolite – Na3AlF6 (ore of aluminium)

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Vishal Baghel

Contributor-Level 10

Kindly go through the solution

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Vishal Baghel

Contributor-Level 10

Above 1350oC, the standard Gibbs free energy formation of Al2O3 from Al is less than that of MgO from Mg. Therefore, above 1350oC, Al can reduce MgO.

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