Ncert Solutions Chemistry Class 12th

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alok kumar singh

Contributor-Level 10

Misch metal consists of Lanthanide metal (? 95%) and iron (? 5%) and traces of S, C, Ca and Al.

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alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

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alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

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alok kumar singh

Contributor-Level 10

The chemical structure shown is 5-Amino-4- (hydroxymethyl)-2-nitrobenzene carbaldehyde.

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alok kumar singh

Contributor-Level 10

(i) Ca (OH)? is used in white wash.
(ii) Plaster of paris is used in making of molds for plaster statues.
(iii) NaCl is used in preparation of washing soda.
(iv) A suspension of Mg (OH)? in water is used in medicine as an antacid under name of milk of magnesia.

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alok kumar singh

Contributor-Level 10

(I) Lucas reagent → Only ZnCl? /Conc. HCl
(II) Dumas method → CuO/Δ
(III) Kjeldahl's method → Conc. H? SO? /Δ
(IV) Heinsberg reagent → C? H? SO? Cl/ aq. NaOH

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alok kumar singh

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Zn, Cd&Hg are purified by fractional distillation process.

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alok kumar singh

Contributor-Level 10

In the ccp lattice of oxide ions effective number of O? ² ions = 8 *? + 6 * ½ = 4
In the ccp lattice,
No. of octahedral voids = 4
No. of tetrahedral voids = 8
Given M? atoms occupies 50% of octahedral voids and M? atoms occupies 12.5 of tetrahedral voids
No. of M? metal atoms = 4 *? /? = 2
No. of M? metal atoms = 8 * ¹²·? /? = 1
∴ Formula of the compound = (M? )? (M? )O?
∴ Oxidation states of metals M? & M? respectively are +2 and +4 .

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alok kumar singh

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Kindly go through the solution

 

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Satyendra Dhyani

Beginner-Level 5

The metal-carbon bonds (M-C) in metal carbonyls are due to the synergic interaction between the metal and carbonyl group. There are two types of bonding between metal and carbonyl group. 

? -bond in Metal Carbonyls: The Carbonyl (CO) ligand donates a lone pair of electrons to the metal center to fill its empty d-filled orbital. This electron density donation is called? -donation.

? -back bond in Metal Carbonyls: This is the case of back bonding. The already filled d-orbitals return the electron density into the empty? * (antibonding) orbital of CO. This electron density donation by the metal is called? -back donation.

Both these comb

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