Coordination Compounds

CoCl₃.NH₃ + AgNO₃ $\stackrel{}{\to }AgC\mathcal{l}\downarrow \left(2mol\right)$  

$\left[Co{\left(N{H}_3\right)}_{5}C\mathcal{l}\right]C{\mathcal{l}}_2+AgN{O}_3\stackrel{}{\to }AgC\mathcal{l}\downarrow \left(2mol\right)$  

x = 5

In H₂O (polar solvent) dibromophenol derivative and in CS₂ (non-polar solvent moneobromo phenol derivate is obtained.

3d => 4d => 5d CFSE increases for the same ligands.

Factual
⇒ leaching methods is used for those metal in which metal is more soluble than impurities and these are Al, Au, Ag, low grade Cu

σ bonded organometallic compound ⇒ M – C
σ-bond
and in π – bonded organo metallic compound
M – C
π bond
In ferrocene, there is π-bond

The given value of µ (spin only)
2.84 = √n (n + 2) BM, So, n = 2
Among the given configurations, d? system in strong field ligand will have 2-unpaired e? in t? g set of orbitals as shown below.

Formation of passive layer of Fe? O? on the surface of Fe and NO? gas is evolved
[Co (NH? )? ]³? is diamagnetic (t? g? eg? ) and is inner orbital complex

[Co (NH? )? ]Cl? and [Ni (NH? )? ]²? are paramagnetic.

[M (AA)? ]? complexes are chiral.

Reaction follows SN1 pathway involving Benzylic carbocation.