P Block Elements
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7.34 Why has it been difficult to study the chemistry of radon?
7.34 Why has it been difficult to study the chemistry of radon?
7.34
It is difficult to study the chemistry of radon because it is a radioactive substance having a half-life (the time period to decompose the substance half to its initial concentration) of only 3.82 days.
Radon belongs to the 18 group elements with chemical formula as Rn. In general, the elements a
7.33
XeF6 + H2O XeO2F2 + HF
Balanced equation: XeF6 + 2H2O XeO2F2 +4HF. The steps for balancing the reaction are as follows:
1. The main element is First, check if the atoms of Xe on both sides are balanced. YES, they are.
2. Then take another element i.e. F. It is not balanced on the right side,
7.32
Helium mixed with oxygen under pressure is given to sea divers for respiration because pure oxygen can be toxic at a great concentration at the depth. Therefore oxygen can be mixed with helium to reduce oxygen concentration while eliminating nitrogen.
The main reason for adding helium to th
7.31
In interhalogen compound ICl and I2 the atoms are bonded by covalent bonds
Reactivity refers to the rate at which a chemical species will undergo reaction in time. For reaction to take place the compound needs to be broken into separate elements first, then the individual elements react with othe
7.30 Name two poisonous gases which can be prepared from chlorine gas.
7.30 Name two poisonous gases which can be prepared from chlorine gas.
7.30
Two poisonous gases that can be prepared with chlorine gas are:
Phosgene (COCl2)
This is how phosphene is formed:
CO + Cl2? COCl2 (in presence of sunlight)
(ii) Mustard gas (Cl-C2H4-S-C2H4-Cl)
(iii) Tear gas (CCl3NO2)
7.29
Moist chlorine is a good reducing agent because it can accept electrons from other species as it is very electronegative.
(iii) The bleaching action of chlorine is due to oxidation by nascent oxygen produced. This nascent oxygen can be produced by
Chlorine dissolves in water in absence of sunligh
7.28 Sea is the greatest source of some halogens. Comment.
7.28 Sea is the greatest source of some halogens. Comment.
7.28
Sea water is a treasure of many elements and halogens are one of them. It contains many compounds of halogen including bromides, iodides, and chlorides. The solid deposits from sea water contain NaCl and Carnalite.
It primarily contains COMMON SALT (2.5% by mass). The deposits of dried up sea be
7.27 Give two examples to show the anomalous behaviour of fluorine.
7.27 Give two examples to show the anomalous behaviour of fluorine.
7.27
The reasons for the anomalous behaviour of fluorine are as follows:
The smallest size of fluorine
The highest electronegativity
Low bond dissociation enthalpy of F-F bond
Non-availability of d-orbitals in its valence shell The anomalous properties are as follows;
Fluorine shows only one oxidation sta
7.26 Considering the parameters such as bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy, compare the oxidising power of F2 and Cl2 .
7.26 Considering the parameters such as bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy, compare the oxidising power of F2 and Cl2 .
7.26
The oxidizing power of an element depends on three factors.
1. Bond dissociation energy
2. Electron gain enthalpy
3. Hydration enthalpy
Fluorine is considered the strongest oxidizing agent compared to all known elements due to its small size (being the first member of 17 group and ionic radii decrea
7.25
H2SO4 is dibasic acid (two replacable H+ ions) . In aqueous solution it dissociates in two steps as follows:
H2SO4 + H2O H3O+ + HSO4 | (Ka1 = very large) |
HSO4 + H2O H3O+ + SO42 | (Ka2 = 1.2 x 10–2) |
The formula for dissociation constants are:

The neutral H2SO4 molecule has more tendency to lose a proton (H+) than the Lowry-Bronsted base (which can donate electron i.e. accept a proton