The p -Block Elements

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Vishal Baghel

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Coke- reducing agent
Diamond- sp³ carbons
Fullerenes- cage like structure
Graphite- used as lubricant

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Vishal Baghel

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Tl? ³ is less stable than Tl? ¹ (inert pair effect). Going down the group 13, stability of lower oxidation state increases. In case of B, Al, Ga and In, higher O.S. +3 remains more stable than lower O.S. +1 . But, in last stable element, thallium (Tl), lower O.S. +1 become more stable than higher O.S. +3 .

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Vishal Baghel

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| H – F | H – Cl | H – Br | H – I |
| :- | :- | :- | :- |
| 1s – 2p | 1s – 3p | 1s – 4p | 1s – 5p |

Down the group size increases
Overlapping decreases
Acidic strength increases

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Vishal Baghel

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For one mole of an ideal gas
C? – C? = R

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Vishal Baghel

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Correct sequence of bond enthalpy of C – X bond is
CH? – F > CH? – Cl > CH? – Br > CH? – I

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Vishal Baghel

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The maximum temperature that can be achieved in blast furnace is upto 2200 K .

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Vishal Baghel

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Due to lanthanoid contraction Zr and Hf has similar atomic and ionic radii.

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Vishal Baghel

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At different positions -NO? affects acidic strength differently. The order of acidic strength is p-nitrophenol > o-nitrophenol > m-nitrophenol.

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Vishal Baghel

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MgH? is an ionic or saline hydride, GeH? is an electron precise hydride with 8 electrons around Ge, B? H? is an electron deficient hydride and HF is electron rich.

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