Chemistry Coordination Compounds

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A
alok kumar singh

Contributor-Level 10

In strong ligand field C o 3 + will have t 2 g 6 e g 0 of configuration and Δ t = 4 9 Δ 0

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A
alok kumar singh

Contributor-Level 10

M A 2 B 2 shows geometrical and not optical isomerism

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V
Vishal Baghel

Contributor-Level 10

Kindly consider the following figure

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Vishal Baghel

Contributor-Level 10

[Ni (C)4)] bonding diagram and energy can be explained by MOT clearly.

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Raj Pandey

Contributor-Level 9

CrCl? ·3NH? ·3H? O gives 3 moles of AgCl precipitate. This means all three Cl? are outside the coordination sphere.
The complex is [Cr (NH? )? (H? O)? ]Cl?
The 3 chloride ions satisfy only primary valency.
secondary valency satisfied by chloride ion = 0

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Vishal Baghel

Contributor-Level 10

Number of GI in [Co (NH? )? (NO? )? ] is 2 i.e, X
Number of GI in [Cr (C? O? )? ]³? is 0 i.e. Y
[X + Y] = 2

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Vishal Baghel

Contributor-Level 10

[MnCl? ]³?
Mn (25) → [Ar] 4s²3d?
Cl? → weak ligand
Mn³? → 3d? i.e. t? g³, eg¹
Hybridization → sp³d² and paramagnetic

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Vishal Baghel

Contributor-Level 10

(A) [PtCl? (NH? )? ], Number of GI = 2


(B) [Ni (CO)? ], Number of G.I = 0 as it is tetrahedral.
(C) [Ru (H? O)? Cl? ] Number of G.I = 2 (Facial and Meridional)


(D) [CoCl? (NH? )? ]? Number of G.I = 2 (Cis and trans)

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alok kumar singh

Contributor-Level 10

Chelation increases stability of complex. Also more the chelation more the stability. Here, [Co (en)? (NH? )? ]Cl? , [Co (en)? ]Cl? and [Co (en) (NH? )? ]Cl? have chelation due to ethylenediamine. Therefore [Co (en)? ]Cl? has the highest chelation so the highest stability.

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Vishal Baghel

Contributor-Level 10

Kindly consider the following figure

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