Chemistry NCERT Exemplar Solutions Class 11th Chapter Nine

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Payal Gupta

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H2O (l)+NH3 (aq) → OH- (aq)+NH4+ (aq)

H2O (l)+H2S (aq) → H3O+ (aq)+HS- (aq)

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Payal Gupta

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2F2 (g)+2H2O → 4H+ (aq)+4F- (aq)+O2 (g)

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Payal Gupta

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In water hybridisation of oxygen is sp3. Angle should be109o (approx.) but due to LP - LP repulsion bond angle reduces to 104.5°.

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Payal Gupta

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Because H2SO4 can activate the decomposition of H2O2.

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Payal Gupta

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With soap, hard water generates scum/precipitate. Soap containing sodium stearate (C117H35COONa) interacts with hard water to form calcium and magnesium stearate (Ca/Mg stearate). As a result, it is unsuitable for laundering. Because of the deposition of salts in the form of scale, it is also hazardous to boilers.

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Payal Gupta

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Hydrogen peroxide is stored in wax lined bottles because decomposes slowly on exposure to light.

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Payal Gupta

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Hydrogen peroxide cannot be concentrated by heating as it can cause bumps on heating. It can be extracted with water and concentrated to ~30% (by mass) by distillation under reduced pressure. It can be further concentrated to ~85% by careful distillation under low pressure. The remaining water can be frozen out to obtain pure H2O2.

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Payal Gupta

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Water has a significantly higher boiling point than hydrogen sulphide because of the presence of strong hydrogen bonds between water molecules, which are absent in hydrogen sulphide due to the lower electronegativity of sulfur compared to oxygen; this means more energy is required to separate water molecules, resulting in a higher boiling point. 

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Payal Gupta

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Water molecules are polar because in the gas phase water is a bent molecule with a bond angle of 104.5°, O-H bond length of 95.7 pm. Oxygen is more elsectronegative  (EN = 3.5 ) than hydrogen (EN= 2.1 ) hence, O-H bond is polar . In the water molecule, two polar O-H nonds area present which are held together at an angle of 104.5 . Due to the resultant of these two dipoles, water molecule is polar and has an dipole moment of 1.84 Debye.

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Payal Gupta

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H2O2 decomposes slowly on exposure to light.

2H2O2→ 2H2O+2O2

In daily life it is used as a hair bleach and as a mild disinfectant. As an antiseptic it is sold in the market as perhydrol.

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