Chemistry NCERT Exemplar Solutions Class 11th Chapter Nine

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(i) Oxidising action in acidic medium:

2Fe²⁺ (aq)+2H⁺ (aq)+H₂O₂ (aq) → 2Fe³⁺ (aq)+2H₂O (l)

PbS (s)+4H₂O₂ (aq) → PbSO₄ (s)+4H₂O (l)

(ii) Reducing action in acidic medium:

2MnO₄^-+6H⁺+5H₂O₂ → 2Mn²⁺+8H₂O+5O₂

HOCl+H₂O₂ → H₃O⁺+Cl^-+H₂O

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H₂O₂ structure in gas phase, dihedral angle is 111.50. H₂O₂ structure in solid phase at 110 k, dihedral angle is 90.20.

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Heavy water can be used as a moderator in nuclear reactors and in exchange reactions for the study of reaction mechanisms. It can be prepared by exhaustive electrolysis of water or as a by-product in some fertilizer industries.

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Hydrogen economy (Hydrogen as fuel):

(i) The electricity cannot be stored in automobiles. It is not possible to store and transport nuclear energy. Hydrogen is an alternative source of energy and hence called the 'hydrogen economy". Hydrogen has some advantages as fuel.

(ii) Available in abundance in combined form as water.

(iii) On combustion produces H₂O. Hence, pollution free.

(iv) H₂O₂ fuel cells give more power.

(v) Excellent reducing agent. Therefore, it can be used as a substitute of carbon in reduction for processes in industry.

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In sodium the last shell electron is in 3s₁ after losing that electron, it can acquire the configuration of Ne. Whereas in hydrogen, the electron is in s-orbital.

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Because of ionization enthalpy, hydrogen resembles more with halogens, is 520 kJ mol^-1, F is 1680 kJ mol^-1and that of His 1312 kJ mol^-1. Like halogens, it forms a diatomic molecule, combining with elements to form hydrides and a large number of covalent compounds.

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Hydrogen has electronic configuration 1s¹. On the one hand, its electronic configuration is similar to that of alkali metals in the first group of the periodic table, which have an outer electronic configuration (ns¹). As a result, hydrogen resembles alkali metals that lose one electron to become unipositive ions.

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(i) The given compound is H₂O₂.

(ii) Textiles, paper pulp, leather, oils, fats, and other products use it as a bleaching agent. In both acidic and alkaline media, it works as an oxidising and reducing agent. It is therefore kept in dark wax-lined glass or plastic containers. As a stabiliser, urea might be used. It is kept away from dust since dust can cause the compound to decompose explosively.

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Because of hydrogen bonding HF is liquid whereas HCl is gas as there is lack of hydrogen bonding in HCl.