Chemistry NCERT Exemplar Solutions Class 11th Chapter Three

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alok kumar singh

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Group

1

Valency

1

Outermost electronic configuration

8s1

Formula of Oxide

M2O

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alok kumar singh

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Transition elements are named so because they form a bridge between s-block elements and p-block elements. Zn, Cd and Hg are among those elements that are dblock elements but they do not exhibit most of the properties of transition elements.

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alok kumar singh

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As the atomic size of F is much smaller which leads to high e- - e - repulsion upon addition of electrons thus its electron gain enthalpy is less than that of Cl.

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alok kumar singh

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Ans: As we move across the periodic table the ionization energy increases because of the increase in the effective nuclear charge and decrease of the shielding effect as more and more electrons get added in the same orbital.

Thus group 1 has lower ionization enthalpy compared to that of group 17 and also group 1 by losing one electron it will acquire the nearest noble gas electronic configuration which also contributes towards its lower ionization enthalpy.

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alok kumar singh

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The following points make long form of periodic table better than Mendeleev's periodic table :-

(a) It is a periodic function of atomic number

(b) Elements are grouped as per there outermost electronic configuration

(c) Proper segregation of metals and non-metals

(d) More appropriate position of group VII.

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alok kumar singh

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This is a Long Answer Type Questions as classified in NCERT Exemplar

Mendeleev's arranged the elements as the periodicity of their atomic weights.

The drawbacks of Mendeleev's periodic table are as follows:-

(a) The position of hydrogen in the periodic table is not specified

(b) Isotopes are not included in the periodic table

(c) Elements with higher atomic mass are placed before the elements with lower atomic mass. For e.g- Co & Ni

(d) Gaps are left in his table considering the fact that more elements are yet to be discovered

(e) Inappropriate position of group VII.

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alok kumar singh

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The group 1 elements are called alkali metals which possess outermost electronic configuration as ns1 .All the elements that have same outermost electron configuration possess similar properties and are placed in the same group.

Atomic number

Symbol

Electronic Configuration

 

3

Li

1s2 2s1

[He]2s1

11

Na

1s2  2s2 2p6 3s2

[Ne]3S1

19

K

1s2 2s2 2p6 3s2 4s1

[Ar]4S1

37

Rb

1s2 2s2 2p6 3s2 3d10 4s2 4p6 5s1

[Kr]5S1

55

87

Cs

Fr

1s2 2s2 2p6 3s2 3d10 4s2 4p6 5d10 5s2 5p6  6s1

[Xe]6s1

[Rn]7s1

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alok kumar singh

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The amount of energy required to remove an electron from the outermost shell of an isolated gaseous atom in its ground state is said to be ionisation enthalpy.

The factors that affect ionization enthalpy of the elements are as follows:

(a) Effective nuclear charge with its increase the ionization enthalpy also increases

(b) Atomic size with its increase the ionization enthalpy decreases

(c) The e-e - repulsion with its increase the ionization enthalpy decreases

(d) Whenever there exists half filled or completely filled orbital than it lead to increase the ionization enthalpy b

...more

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alok kumar singh

Contributor-Level 10

This is a Long Type Questions as classified in NCERT Exemplar

The factors that affects electron gain enthalpy are as follows:

(a) Effective nuclear charge with its increase the electron gain enthalpy also increases

(b) Atomic size with its increase the electron gain enthalpy decreases

(c) The e-e - repulsion with its increase the electron gain enthalpy decreases

(d) Whenever there exists half filled or completely filled orbital than it lead to decrease the electron gain enthalpy because it leads to give extra stability to the atom due to symmetry

The electron gain enthalpy decreases down the group and increases across the period.

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