Chemistry

.2g of nitrous oxide (N₂O) gas is cooled at a constant pressure of 1 atm from 310 K to 270 K causing the compression of the gas from 217.1mL to 167.75mL. The change in thermal energy of the process, $Δ U$ is '-x' J. The value of 'x' is________. [Nearest Integer]

(Given : atomic mass of N = 14 g mol^-1 and of O = 16 g mol^-1.

Molar heat capacity of N₂O is 100 J K^-1 mol^-1)

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Contributor-Level 10

Moles of N₂O = $\frac{2.2}{44} = \frac{1}{20}$

$Δ H = n C_{p} Δ T = \frac{1}{20} * 100 (- 40) = - 200 J$

$Δ U = q_{p} + w$

$w = - P_{e x t} . Δ V$

$w = - 1 \frac{(167.75 - 217.1)}{1000} * 101.3 J = + 5 J$

$Δ U = - 200 + 5 = 195 J$

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Chemistry Class 12th

Which one of the lanthanoids given below is the most stable in divalent form?

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Contributor-Level 9

Valence shell electronic configuration of Eu in +2 O.S is,

$E u^{2 +} = 6 s^{0} 4 f^{7}$

It has half filled f-sub shell and stable.

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Given below are two statements:

Statement I : The pentavalent oxide of group-15 element, E₂O₅, is less acidic than trivalent oxide, E₂O₃, of the same element.

Statement II : The acidic character of trivalent oxide of group 15 elements, E₂O₃ decreases down the group.

In light of the above statements, choose most appropriate answer form the options given below:

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Contributor-Level 9

Pentavalent oxides of group – 15 elements, E₂O₅ is more acidic than trivalent oxides, E₂O₃ of the same element.

Acidic strength of trivalent oxides decreases down the group as metallic strength increases.

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Chemistry Structure of Atom

A box contains 0.90g of liquid water in equilibrium with water vapour at 27°C. The equilibrium vapour pressure of water at 27°C is 32.0 Torr. When the volume of the box is increased, some of the liquid water evaporates to maintain the equilibrium pressure. If all the liquid water evaporates, then the volume of the box must be________ litre. [Nearest Integer]

(Given : R = 0.082 L atm K^-1 mole^-1)

(Ignore the volume of the liquid water and assume water vapours behave as an ideal gas.)

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Contributor-Level 10

V = $\frac{n R T}{P} = \frac{0.90 * 0.0821 * 300}{18 * 32} * 760 = 29.21 ≅ 29$

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a year ago

Nitrogen gas is obtained by thermal decomposition of

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Contributor-Level 9

N₂ gas is obtained by thermal decomposition of Ba (N₃)₂ as,

$B a {(N_{3})}_{2} \to_{}^{Δ} B a + 3 N_{2} ↑$

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A white precipitate was formed when BaCl₂ was added to water extract of an inorganic salt. Further, a gas 'X' with characteristic odour was released when the formed white precipitate was dissolved in dilute HCl. The anion present in the inorganic salt is

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Contributor-Level 10

$B a C l_{2} + S O_{3}^{2 -} \overset{}{\to} \underset{W h i t e}{B a S O_{3}} ↓ \overset{d i l . H C l}{\to} \underset{\begin{array}{l} b u r n i n g s u l p h u r \\ l i k e s m e l l \end{array}}{S O_{2} ↑}$

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a year ago

Dihydrogen reacts with CuO to give

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Contributor-Level 9

$C u O + H_{2} \to C u + H_{2} O$

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Chemistry Class 12th

The mixture of chloroxylenol and terpineol is an example of

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Contributor-Level 10

Antiseptic Dettol is mixture of chloroxylenol and terpineol

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Chemistry Class 12th

Given are two statements one is labeled as Assertion A and other is labeled as Reason R.

Assertion A : Magnesium can reduce Al₂O₃ at a temperature below 1350°C, while above 1350°C aluminium can reduce MgO

Reason R : The melting and boiling points of magnesium are lower thatn those of aluminium.

In light of the above statements, choose most appropriate answer for the options given below:

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Contributor-Level 9

Below 1350° C, Mg can reduce Al₂O₃ and above 1350°C, Al can reduce MgO (from Ellingham diagram).

Melting and boiling point of Mg are lower than that of Al.

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Element “E” belongs to the period 4 and group 16of the periodic table. The valence shell electron configuration of the element, which is just above “E” in the group is

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