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Payal Gupta

Contributor-Level 10

1.4 In order to answer the question, we need to know the balanced equation for the combustion of carbon in dioxygen/air, which can be written as:

C (s) + O2 (g) à CO2 (g)

(i) We can see from the above equation,

1 mole of carbon reacts with 1 mole of oxygen to produce 1 mol of carbon dioxide.

In air, combustion is complete.

Therefore, CO2 produced from combustion of 1 mole of carbon= Molar mass of CO2= 44 g

(ii) As only 16 g of dioxygen is available, it can combine only with 0.5 mole of carbon, i.e., dioxygen is the limiting reactant.

Hence, CO2 produced = 22 g

Here, dioxygen acts as the limiting reagent.

(iii) Here again, dioxygen is

...more

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Vishal Baghel

Contributor-Level 10

(a) CO32-  (sp2) (b) Diamond (sp3) (c) Graphite (sp2)

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Payal Gupta

Contributor-Level 10

1.3 We are given that the percentage of iron by mass is 69.9% and the percentage of oxygen by mass is 30.1%.

Since we have relative moles of both elements, we can calculate the simpler molar ratio of iron to oxygen

= 1.25: 1.88

Divide by the smaller value to both

= 1.25/1.25: 1.88/1.25

= 1: 1.5

= 2: 3

So, now we can write the empirical formula of iron oxide as Fe2O3.

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New answer posted

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Vishal Baghel

Contributor-Level 10

Electron deficient compounds are those in which the central atom in their molecule has the tendency to accept one or more electron pairs. They are also known as Lewis acid. BCl3 and SiCl4 both are electron deficient species.
Since, in BCl3, B atom has only six electrons. Therefore, it is an electron deficient compound.
In SiCl4 the central atom Si has 8 electrons but it can expand its covalency beyond 4 due to the presence of d-orbitals.

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Vishal Baghel

Contributor-Level 10

Aluminium reacts with acid as well as base. This shows amphoteric nature of aluminium.
2Al (s) + 6HCl (dil.) 2AlCl3 (aq) + 3H2 (g)
2Al (s) + 2NaOH (aq) + 6H2O (l) 2Na+ [Al (OH)4] (aq) + 3H2 (g)

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Payal Gupta

Contributor-Level 10

1.2 Molar mass of Na2SO4= (2 x Atomic mass of Sodium) + Atomic mass of Sulphur + (4 x Atomic mass of Oxygen)

= (2x 23) + 32 + (4x 16)

= 46 + 32 + 64

= 142 g/mol

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8 months ago

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Vishal Baghel

Contributor-Level 10

In BF3, boron is sp2 hybridized.
? shape of BF3 = planar.
In [BH4], boron is sp3 hybridized, thus the shape is tetrahedral.

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8 months ago

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Vishal Baghel

Contributor-Level 10

On heating boric acid above 370 K, it forms metaboric acid, HBO2 which on further heating yields boric oxide B2O3.

H3B2O3 → HBO2 → B2O3

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Vishal Baghel

Contributor-Level 10

Boric acid is a Lewis acid since it accepts electrons from hydroxyl ion of H2O molecule. It is not a protic acid.
B (OH)3 + 2HOH → [B (OH)4] + H3O+

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