Hydrocarbons

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Payal Gupta

Contributor-Level 10

This is a multiple choice answer as classified in NCERT Exemplar

(iv) C > B > D > A

The boiling point increases with the increase in the length of the side chain. However, with the branching, the boiling point decreases due to the decrease in the surface area.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The reaction is

The alkane is

The tertiary bromide is

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The 2-methylpropane would lead to two types of radicals.

Among the two 3o radical is most stable as it contains 9 ∝ -hydrogen whereas 1o radical contains only 1 ∝ -hydrogen.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

It is a Wurtz reaction where alkane is formed.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The structure of 2-methylbutane is 

2-methylbutane

 

Total number 

Total amount of monochlorinated

Product

% of monochlorinated product

9

9

41.7

2

7.6

35.2

1

5

23.1

 

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Electrophiles

Nucleophiles

(iii), (iv), (v)

(i), (ii), (vi), (vii), (viii)

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

In presence of (Ph-CO-O)2it lead to CH3-CH2-CH2Br as the reaction undergo by free radical mechanism

However in absence of (Ph-CO-O)2 the reaction undergo by carbocation intermediate thus lead to give CH3-CHBr-CH3

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

New answer posted

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The nitro group strongly deactivate the benzene towards the electrophilic substitution reaction due to the -R and -I effect

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Due to the +R effect halogens are ortho and para directing groups.

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