Ncert Solutions Chemistry Class 11th
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12.60. Mention the rules to be applied while writing resonance structures.
12.60. Mention the rules to be applied while writing resonance structures.
The resonance structures have
(i) The same positions of nuclei, and
(ii) The same number ofunpaired electrons.
12.59. What do you understand by resonance effect? Name the two types of it.
12.59. What do you understand by resonance effect? Name the two types of it.
The resonance effect is defined as 'the polarity produced in the molecule by the interaction of two π -bonds or between a π -bond and lone pair of electrons present on an adjacent atom'. The effect is transmitted through the chain. There are two types of resonance or mesomeric effect designated as +
12.58. What do you understand by conjugated system in organic chemistry?
12.58. What do you understand by conjugated system in organic chemistry?
The presence of alternate single and double bonds in an open chain or cyclic system is termed as a conjugated system. These systems often show abnormal behaviour. The examples are 1, 3- butadiene, aniline and nitrobenzene etc. In such systems, the π -electrons are delocalised and the system develop
12.57. Explain hyperconjugation effect. Is hyperconjugation a temporary effect?
12.57. Explain hyperconjugation effect. Is hyperconjugation a temporary effect?
Hyperconjugation is a general stabilising interaction. It involves delocalisation of σ electrons of C—H bond of an alkyl group directly attached to an atom of unsaturated system or to an atom with an unshared p orbital. The σ electrons of C—H bond of the alkyl group enter into partial conjugation wi
Steam distillation is applied to separate substances which are steam volatile and are immiscible with water. In steam distillation, steam from a steam generator is passed through a heated flask containing the liquid to be distilled. The mixture of steam and the volatile organic compound is condensed
12.5. Name the methods for separation of the following:
(i) mixture of two organic compounds having different solubilities in the same solvent
(ii) naphthalene from kerosene oil
(iii) organic liquid that decomposes below its boiling point
12.5. Name the methods for separation of the following:
(i) mixture of two organic compounds having different solubilities in the same solvent
(ii) naphthalene from kerosene oil
(iii) organic liquid that decomposes below its boiling point
(i) By fractional crystallisation
(ii) Simple distillation
(iii Distillation under reduced pressure.
12.54. Mention one difference between a homolytic and a heterolytic cleavage.
12.54. Mention one difference between a homolytic and a heterolytic cleavage.
A heterolytic cleavage yields carbocations or carbanions, while a homolytic cleavage gives free radicals as reactive intermediate.
The resonance effect is defined as 'the polarity produced in the molecule by the interaction of two π-bonds or between a π -bond and lone pair of electrons present on an adjacent atom'. The effect is transmitted through the chain. There are two types of resonance or mesomeric effect designated as R
Buckminsterfullerene is a common name given to the newly discovered C60 cluster (a form of carbon) noting its structural similarity to the geodesic domes popularised by the famous architect R. Buckminster Fuller.
Questions and Answers
12.51.Explain differential extraction.
Questions and Answers
12.51.Explain differential extraction.
When an organic compound is present in anaqueous medium, it is separated by shaking it with an organic solvent in which it is more soluble than in water. The organic solvent and the aqueous solution should be immiscible with each other so that they form two distinct layers which can be separated by