Ncert Solutions Chemistry Class 11th
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12.50. A nucleophile
(a) Brings an electron pair to thereactive site
(b) Takes away anelectron pair from reactive site
(c) Brings nucleus of one atom near the nucleus of another atom
(d) Brings electrons of one atom near the electrons of another atom
12.50. A nucleophile
(a) Brings an electron pair to thereactive site
(b) Takes away anelectron pair from reactive site
(c) Brings nucleus of one atom near the nucleus of another atom
(d) Brings electrons of one atom near the electrons of another atom
(a) Brings an electron pair to the reactive site
12.3. Nitrogen is estimated by
(a) Carius method (b) Dumas method(c) Kjeldahl’s method (d) both b and c
12.3. Nitrogen is estimated by
(a) Carius method (b) Dumas method(c) Kjeldahl’s method (d) both b and c
MCQs
12.46 Hyperconjugation is a
(a) permanent effect (b) temporary effect (c) dual effect (d) none
MCQs
12.46 Hyperconjugation is a
(a) permanent effect (b) temporary effect (c) dual effect (d) none
12.5. Assertion: Electromeric effect is a permanent effect.
Reason: Organic compounds having a multiple bond show this effect in the presence of an attacking reagent.
12.5. Assertion: Electromeric effect is a permanent effect.
Reason: Organic compounds having a multiple bond show this effect in the presence of an attacking reagent.
(d) Electromeric effect is a temporary effect. The organic compounds having a multiple bond (a doubleor triple bond) show this effect in the presence of an attacking reagent only. It is defined as the complete transfer of a shared pair of? -electrons to one of the atoms joined by multiple bond on t
12.44. Assertion: The energy of actual structure of the molecule(the resonance hybrid) is lower than that of anyof the canonical structures.
Reason: Resonance is particularly important when the contributing structures are equivalent in energy.
12.44. Assertion: The energy of actual structure of the molecule(the resonance hybrid) is lower than that of anyof the canonical structures.
Reason: Resonance is particularly important when the contributing structures are equivalent in energy.
(b) The difference in energy between the actual structure and the lowest energy resonance structure is called the resonance stabilisation energy or simply the resonance energy. The more the number of important contributing structures, the more is the resonance energy.
12.43.Assertion: In homolytic cleavage, the movement of a single electron takes place instead of an electron pair.
Reason: A homolytic cleavage yields carbocations or carbanions.
12.43.Assertion: In homolytic cleavage, the movement of a single electron takes place instead of an electron pair.
Reason: A homolytic cleavage yields carbocations or carbanions.
(c) In homolytic cleavage, one of the electrons of the shared pair in a covalent bond goes with each of the bonded atoms. Thus, in homolytic cleavage, the movement of a single electron takes place instead of an electron pair.
A heterolytic cleavage yields carbocations or carbanions, while a homolyti
12.40. The reaction:
CH3CH2I + KOH (aq) → CH3CH2OH + KI is classified as:
(a) electrophilic substitution (b) nucleophilic substitution
(c) elimination (d) addition
12.40. The reaction:
CH3CH2I + KOH (aq) → CH3CH2OH + KI is classified as:
(a) electrophilic substitution (b) nucleophilic substitution
(c) elimination (d) addition
(b) It is a nucleophilic substitution reaction. KOH (aq) provides OH- ion for the nucleophile attack.