Ncert Solutions Chemistry Class 11th

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Vishal Baghel

Contributor-Level 10

(b) Both the statements are correct but not the reason for the assertion.

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Payal Gupta

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1.37. (c) Equal moles of different substances contain same number of constituent particles but equal weights of different substances do not contain the same number of constituent particles due to the difference in their molar mass.

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Vishal Baghel

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(d) The ionization enthalpies of the alkali metals are considerably low and decrease down the group from Li to Cs. This is because the effect of increasing size outweighs the increasing nuclear charge, and the outermost electron is very well screened from the nuclear charge.

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Payal Gupta

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1.36. The molar mass of MnO2is 87g and the molar mass of HCl is 36.5 g.

According to the equation, 4 moles of HCl (i.e. 4 x 36.5g = 146 g) reacts with 1 mol of MnO2 (87g).

So, for 5.0 g of MnO2 will react with:

= 5 x146/87 = 8.40 g of MnO2

Therefore, 8.4 g of HCl will react with 5 g of MnO2.

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Payal Gupta

Contributor-Level 10

1.35. Step 1: 0.75 M HCl means 0.75 mol per 1000 mL or 0.75 x 36.5 g in 1000 mL.

i.e. 1000 mL of 0.75 M HCl contains 0.75 x 36.5 g HCl

Therefore, 25 mL of 0.75 M HCl contains 0.75 x 36.5 x 25/ 1000 g = 0.6844 g


Step 2: To calculate mass of CaCO3reacting completely with 0.6844 g of HCl
CaCO3  (s) + 2HC1 (aq)———>CaCl2 (aq) +CO2 (g) + H2O
2 mol of HCl, i.e., 2 x 36.5 g = 73 g HCl react completely with CaC0= 1 mol = 100 g

Therefore, 0.6844 g HCl will react completely with CaCO= 100/73 x 0.6844 g = 0.938 g

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Payal Gupta

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1.34.  (i) 1 mole (44 g) of CO2 will have 12 g carbon.

So, 3.38 g of CO2 will have carbon = 12g/44g * 3.38

= 0.9217 g

18 g of water will have 2 g of hydrogen.

So, 0.690 g of water contain hydrogen = 2g/18g * 0.6902g

= 0.0767 g

Since carbon and hydrogen are the only constituents of the compound, the total mass of the compound is:

= 0.9217 g + 0.0767 g

=0.9984 g

So, the percentage of Carbon in the compound = 0.9217/0.9984 * 100 = 92.32%

Now, percentage of Hydrogen in the compound = 0.0767/0.9984 * 100 = 7.68%

Moles of carbon in the compound = 92.32/12=7.69

Moles of hydrogen in the compound = 7.68/1=7.68

Since, we ha

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Payal Gupta

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1.33.  (i) 52 moles of Ar

Ans:1 mole of Ar = 6.022 * 1023 atoms of Ar

Therefore, 52 mole of Ar = 52 * 6.022 * 1023 atoms of Ar= 3.131 * 1025 atoms of Ar

(ii) 52 u of He

Ans:1 atom of He = 4u of the He

Or, 4 u of He = 1 atom of He

So, 52 u of He = 52/4 atom of He = 13 atoms of He.

(iii) 52 g of He

Ans:4g of He = 6.022 * 1023 atoms of He

So, 52g of He = 6.022 * 1023 * 52/4 atoms of He

= 7.8286 * 1024 atoms of He

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