Ncert Solutions Chemistry Class 12th

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Vishal Baghel

Contributor-Level 10

CoCl3.NH3 + AgNO3   A g C l ( 2 m o l )

[ C o ( N H 3 ) 5 C l ] C l 2 + A g N O 3 A g C l ( 2 m o l )            

x = 5

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Vishal Baghel

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H2 (g) + Cu2+ (aq)   2H+ (aq) + Cu (s)

  E c e l l = E c e l l 0 2 . 3 0 3 R T n f l o g Q              

              0.31 = 0.34 -   0 . 0 6 2 l o g [ H + ] C u 2 +

[ C u 2 + ] = 1 0 7 ( ? [ H + ] = 1 0 3 )        

              x = 7

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Vishal Baghel

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Kindly consider the following figure

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Vishal Baghel

Contributor-Level 10

 

Aniline show acid-base reaction with AlCl3

aniline is a Lewis base while AlCl3 acts as lewis acid.

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Vishal Baghel

Contributor-Level 10

 

With AlCl3, alkyl halide will form cabocation which will show rearrangement.

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Vishal Baghel

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In this carbocation +M effect of -OCH3 group stabilizes the carbocation.

While in option (A) and (B), +M of -OCH3 will not work but in option (C), +M of -OCH3 works so due to more delocalization in option (D), it is more stable.

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Vishal Baghel

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Complete reaction of acid rain is

2 S O 2 + O 2 + 2 H 2 O 2 H 2 S O 4 ( a c i d r a i n )

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Vishal Baghel

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Borax forms basic buffer solution in aqueous medium.

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Vishal Baghel

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Baking soda = NaHCO3

Washing soda = Na2CO3. 10H2O

Caustic soda = NaOH

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Vishal Baghel

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From the given structure of CuSO4 . 5H2O Cu (II) ion and oxygen bonds are present but ligands coordinating with Cu (II) ion are not O and S both.

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