Ncert Solutions Chemistry Class 12th

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Vishal Baghel

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Kindly go through the solution

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alok kumar singh

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1.38 Kindly consider the following

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alok kumar singh

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15.22 Kindly consider the following

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alok kumar singh

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15.17 Kindly consider the following

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alok kumar singh

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Ans. Kindly consider the following

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alok kumar singh

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This is a Long Answer Type Questions as classified in NCERT Exemplar

Ans: While manufacturing tyre rubber, 5 % sulfur is used as a crosslinking agent. A natural linear polymer of 2-methyl-1, 3-butadiene becomes hard on treatment with sulfur and forms vulcanised rubber. The structure of the product formed is,

 

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alok kumar singh

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Thermoplastic polymer

Thermoplastic polymers are linear or slight branched-chain polymers. In this type of polymer, the strong intermolecular force of attraction is present between elastomers and fibers. This type of polymer softens on heating and hardens on cooling. For example, polythene, polystyrene and polyvinyl.

Thermosetting polymer

Thermosetting polymers are cross-linked polymers. These polymers on heating undergo cross-linking in molds. They become infusible on heating so, cannot be reused again. For example, Bakelite and urea-formaldehyde resins.

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alok kumar singh

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This is a Long Answer Type Questions as classified in NCERT Exemplar

Ans:

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alok kumar singh

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The oldest synthetic polymers are phenol-formaldehyde polymers. These are made by combining phenol and formaldehyde in the presence of either an acid or a base catalyst. The reaction begins with the formation of o-and/or p hydroxymethyl phenol derivatives, which then react with phenol to form compounds with shaving rings connected by –CH2 groups. The first product could be a linear product, such as Novolac.

When heated with formaldehyde, Novolac crosslinks to form Bakelite, an infusible solid mass.

It is used to make combs, phonograph records, electrical switches, and

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alok kumar singh

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In rubber, the polymer chain are held together by the weakest force of attraction. While, in plastic, the strong intermolecular force of attraction is present between elastomers and fibres.

In rubber, a few crosslinks are introduced between the chain, while plastics are linear or slightly branched molecules which gets soft on heating and hard on cooling.

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