Ncert Solutions Chemistry Class 12th

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alok kumar singh

Contributor-Level 10

Sphalarite             ZnS

Calamine              ZnCO3

Galena                  PbS

Siderite                FeCO3

 

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alok kumar singh

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Density, ρ = 7 . 6 2 g c m 3  

Cell edge, a = 0.4518nm = 0.458 * 10-7 cm

Effective number of atoms, Z = 4 for CCP.

Using ; ρ = Z * A N A * a 3  

ρ = 4 * A 6 . 0 2 2 * 1 0 2 3 * ( 0 . 4 5 8 * 1 0 7 ) 3              

7 . 6 2 = 4 * A 6 . 0 2 2 * ( 0 . 4 5 1 8 ) 3 * 1 0 2              

A = 105.79 g/mol

Ans. is 106 (the nearest integers)

 

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alok kumar singh

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Reducing power for group-15 hydrides increases down the group, so BiH3 is the strongest reducing agent.

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alok kumar singh

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Sulphide ion (s2-) form ores commonly with Pb & Ag as PbS and Ag2S

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alok kumar singh

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Kindly go through the solution

 

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alok kumar singh

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Compound A is phenol since phenol gives dark green colour with FeCl3.

 

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alok kumar singh

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Depression in freezing point will be maximum for Al2 (SO4)3 since its Van't Hoff factor is the highest. So its solution will have the lowest freezing point.

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alok kumar singh

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When AgNO3 is added to Kl solution, precipitate of Agl is formed which adsorb I- ion from

Dispersion medium to give negatively charged sol

A g N O 3 + K l A g l + K N O 3

Agl/l-- negatively charged sol.

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alok kumar singh

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Esters on treating with excess CH3MgBr followed by hydrolysis gives 3° alcohol.

 

 

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alok kumar singh

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Reaction of acetone and semicarbazide

 

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