Solid State

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New question posted•a year ago
New answer posted•a year ago
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a year ago

1.34 (i) The efficiency of packing in case of simple cubic unit cell is given below: 
A simple cubic unit cell contains one atom per unit cell.
Also, a=2r, where a is the edge length and r is the radius of atom. Total volume of unit cell = a3
Packing efficiency = Volume of one sphere / Total volum

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New answer posted•a year ago
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a year ago

(i) Both metallic and ionic crystals have strong forces of attraction between their atoms or ions. In metallic crystals there is a strong metallic bond present between electrons and positively charged ions. In ionic crystals there are strong ionic bonds between anions and cations. Both of them cond

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New answer posted•a year ago
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a year ago

1.32 Number of corner atoms per unit cell
= 8 corners atoms ×18 atom per unit cell
=8 × 18 = 1 atom
Number of face face centred atoms per unit cell
= 6 face centred atoms × 12 atom per unit cell
= 6 × 12 = 3 atoms
∴ Total number of atoms (lattice point) = 1 + 3 = 4
(ii) As in (i)
No. of lattice points = 4
(i

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New answer posted•a year ago
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a year ago

1.31 (i) In hexagonal close packing (hcp), the spheres of the third layer are vertically above the spheres of the first layer. It means tetrahedral voids of the second layer are covered by the spheres of the third layer. The AB. type.In cubic close packing (ccp), the spheres of third layer cover the

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a year ago

1.30 Stability of a crystal is directly proportional to the magnitude of its melting points. Higher is the magnitude of forces holding the constituent particles together, higher will be the melting point and higher will be the stability. Thus ionic crystals (NaCl, KNO3 etc.) have very high melting p

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a year ago

1.30 Knowing the density of an unknown metal and the dimension of the unit cell, the atomics mass of the metal can be determined.

Let, Atomic mass of element

(M)=d* a3* NA x Z

Where, d = density

  • a3= volume of the unit cell
  • NA = Avogadro's number
  • Z= number of atoms present in one unit cell.
  • Density of the

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a year ago

1.28 Coordination number is the number of the nearest neighbors with which a given atom is in contact. In an 
ionic crystal, the coordination number of an ion refers to the number of oppositely charged ions that 
surround that ion.
The coordination number of atoms in a
(a) Cubic close-packed

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New answer posted•a year ago
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a year ago

1.27 The different solids are classified below:
a) Ionic solids: Ammonium phosphate (NH4)3PO4), LiBr
b) Metallic solid: Brass, Rb
c) Molecular solids: Tetraphosphorous decaoxide (P4O10), Iodine (I2), P4
d) Network (covalent) solids: Graphite, SiC, Si
e) Amorphous solid: Plastics

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New answer posted•a year ago
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a year ago

1.26 Quartzis crystalline solid with long range order and glass is amorphous solid (or pseudo solid or super cooled liquid) with short range order and has a tendency to flow. When quartzis heated, it can be converted into glass.

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