The p -Block Elements

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9 months ago

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Vishal Baghel

Contributor-Level 10

In BF3, central atom has only six electrons after sharing with the electrons of the F
atoms. It is an electron-deficient compound and thus behaves as a Lewis acid.

New answer posted

9 months ago

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V
Vishal Baghel

Contributor-Level 10

BCl3 is quite stable. Because there is absence of d- and f-electrons in boron three valence electrons (2s2 2px1) are there for bonding with chlorine atom. In Tl the valence s-electron (6s2) are experiencing maximum inert pair effect. Thus, only 6p1 electron is available for bonding. Therefore, BCl3 is stable but TlCl3 is comparatively unstable.

New answer posted

9 months ago

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V
Vishal Baghel

Contributor-Level 10

(i) B to Tl
Common oxidation states are +1 and +3. The stability of +3 oxidation state decreases from B to Tl while +1 oxidation state increases from B to Tl.

(ii) C to Pb
The common oxidation states are +4 and +2. Stability of +4 oxidation state decreases from C to Pb.

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