The p -Block Elements

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A
alok kumar singh

Contributor-Level 10

Be2Cl4 is Lewis acid and Al2Cl6 has complete octet. Be and Al are amphoteric metal therefore dissolve in acid as well as alkaline solution and form beryllate and aluminate ions in excess alkali.

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V
Vishal Baghel

Contributor-Level 10

( N H 4 ) 2 C r 2 O 7 Δ N 2 + C r 2 O 3 + 4 H 2 O

K M n O 4 + H C l M n C l 2 + K C l + C l 2 + H 2 O

A l + N a O H + H 2 O N a [ A l ( O H ) 4 ] + H 2

N a N O 3 N a N O 2 + O 2

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P
Payal Gupta

Contributor-Level 10

KO2, NO2, ClO2, NO are paramagnetic.

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Payal Gupta

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A g C l + 2 N H 3 [ A g ( N H 3 ) 2 ] C l ( S o l u b l e c o m p l e x )

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alok kumar singh

Contributor-Level 10

Phosphorous can expand its covalency beyond 4, as it has vacant 3d orbitals. Nitrogen can't expand its covelency beyond 4, as it does not posses vacant 3d- orbitals.

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Vishal Baghel

Contributor-Level 10

Enamel has calcium hydroxyl apatite [Ca10 (PO4)6 (OH)2], CaCO3, CaF2 and Mg3 (PO4)2

Ca2+, P5+ and F- are present

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Vishal Baghel

Contributor-Level 10

NF3 is stable due to high N-F bond energy.

Other halides of nitrogen (NCl3 NBr3, Nl3) are explosive

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V
Vishal Baghel

Contributor-Level 10

B2H6 has 4 2 c -2e bonds and 2 3c-2e bonds.

Bridging (B-H) bonds have more value of bond- length then terminal (B – H) bonds

Bridging bonds are in one plane, but terminal bonds are in perpendicular plane.

Due to presence of (3c-2e) bonds, it behaves as electrons deficient and prone to get attached by lewis base.

3 N a B H 4 + 4 B F 3 Δ 3 N a B F 4 + 2 B 2 H 6                

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Vishal Baghel

Contributor-Level 10

Acidic oxide => Cl2O7

Neutral oxide => N2O, NO

Basic oxide => Na2O

Amphoteric oxide => As2O3

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Vishal Baghel

Contributor-Level 10

Kindly go through the solution

(b) sp2.

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