Alcohol Phenol And Ethers

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

When phenol is treated with bromine water, it forms the white precipitate of 2, 4, 6-tribromophenol. In the bromination reaction of phenol, water is ionized. And also bromine gets ionized to produce bromonium ions to a larger extent. Phenol gets ionized to produce an ortho-para directing phenoxide ion. Bromine water is mostly used as a test for C=C double bond. During this reaction white precipitates form at the end and bromine water is decolourised.

Hence, the formation of bromonium ions and strong ortho-para directing species indicates that the product formation is

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Out of o-nitrophenol and o-cresol, o-nitrophenol  is more acidic due to the -I effect and -R effect of -NO2 group as the -NO2 group is an electron withdrawing group whereas the -CH3 group is electron releasing group and has +I effect on the conjugate base which increases the electron density and decreases the polarity of O-H bond and hence less acidic.

Fig: The -I effect of NO2 group and + I effect of CH3 group on the polarity of O-H bond

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Payal Gupta

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This is a short answer type question as classified in NCERT Exemplar

Out of o-nitrophenol and p-nitrophenol, o-nitrophenol is more volatile due to presence of intramolecular hydrogen bonding in o-nitrophenol whereas p-nitrophenol has intermolecular hydrogen bonding.

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Payal Gupta

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This is a short answer type question as classified in NCERT Exemplar

The strong oxidising agents such as acidified KMnO4 or  K2Cr2O7 reagents are used for the conversion of ethanol to ethanoic acid. These reagents are so strong that they convert the alcohols to carboxylic acids.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The reagent used for the conversion of ethanol to ethanal is pyridinium chlorochromate (PCC) which is a complex formed by CrO3, pyridine and HCl which converts the primary alcohols to aldehydes.

CH3—CH2—OH CH3—CHO

Ethanol                                   Ethanal

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

2-chloroethanol is more acidic than ethanol  because the conjugate base  of  2-chloroethanol   is more stable than that of ethanol due to the -I effect of chlorine atom.

Stability:   Cl—CH2—CH2—OΘ           >                     CH3—CH2—OΘ

Acidity:     Cl—CH2—CH2—OH   >                     CH3—CH2—OH

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The reagent pyridinium chlorochromate (PCC) is a complex formed by CrO3, pyridine and HCl converts the secondary alcohol to ketone without oxidising the double bond.

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

Alcohols such as ethanol  are made unfit for consumption by adding some additives like copper sulphate and pyridine which gives a foul smell, and  bad taste  to alcohol, it is known as denatured alcohol. 

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Payal Gupta

Contributor-Level 10

This is a short answer type question as classified in NCERT Exemplar

The solubility of alcohol in water depends upon the following factors:

(a) Hydrogen bonding: Alcohols form hydrogen bonding with water due to the presence of -OH group in alcohol and hence alcohols are soluble in water. 

(b) Size  of alkyl or aryl group: The alkyl and aryl group are hydrophobic in nature and larger the size of  alkyl or aryl group of alcohol lesser will be the solubility of alcohol in water.

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Payal Gupta

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This is a short answer type question as classified in NCERT Exemplar

3-Methylpent-2-ene-1,2-diol

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