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4 months ago

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A
alok kumar singh

Contributor-Level 10

Limit (n→∞) [[r] + [2r] + . + [nr]] / n²
We know that x - 1 < [x] x.
Summing from k=1 to n for [kr]:
Σ(kr - 1) < [kr] (kr)
rΣk - Σ1 < [kr] rk
r(n(n+1)/2) - n < [kr] r(n(n+1)/2)

Divide by n²:
(r/2)(1 + 1/n) - 1/n < ([kr])/n (r/2)(1 + 1/n)

As n → ∞, both the left and right sides approach r/2.
By the Squeeze Theorem, the limit is r/2.

New answer posted

4 months ago

0 Follower 9 Views

A
alok kumar singh

Contributor-Level 10

cos(x)(3sin(x) + cos(x) + 3)dy = (1 + ysin(x)(3sin(x) + cos(x) + 3))dx
This seems mistyped. A more likely form is:
dy/dx - (sin(x)/(cos(x)))y = 1 / (cos(x)(3sin(x) + cos(x) + 3))
dy/dx - tan(x)y = sec(x) / (3sin(x) + cos(x) + 3)

The integrating factor (I.F.) is:
I.F. = e^∫(-tan(x))dx = e^(ln|cos(x)|) = cos(x).

Multiplying by I.F.:
d(y*cos(x))/dx = 1 / (3sin(x) + cos(x) + 3)

y*cos(x) = ∫ dx / (3sin(x) + cos(x) + 3)

Using Weierstrass substitution, let t = tan(x/2):
sin(x) = 2t/(1+t²), cos(x) = (1-t²)/(1+t²), dx = 2dt/(1+t²)

∫ (2dt/(1+t²)) / (3(2t/(1+t²)) + (1-t²)/(1+t²) + 3)
= ∫ 2dt / (6t + 1 - t² + 3 + 3t²) = ∫ 2dt / (2t² + 6t

...more

New answer posted

4 months ago

0 Follower 2 Views

R
Raj Pandey

Contributor-Level 9

For the complex K? [Cr (oxalate)? ], the central metal ion is Cr³?

Electronic configuration of Cr (24) is [Ar] 4s¹3d?

Electronic configuration of Cr³? is [Ar] 4s?3d³.

The number of unpaired electrons in Cr³? is 3.

New answer posted

4 months ago

0 Follower 8 Views

A
alok kumar singh

Contributor-Level 10

Given the function:
f(x) = { x(2 - sin(1/x)), if x ≠ 0
{ 0, if x = 0

For x < 0: f(x) = x(2 - sin(1/x))

For x > 0: f(x) = x(2 - sin(1/x))

The derivative f'(x) for x ≠ 0 is:
f'(x) = 1*(2 - sin(1/x)) + x*(-cos(1/x))*(-1/x²) = 2 - sin(1/x) + (1/x)cos(1/x)

The text calculates the derivative differently:
For x < 0: f'(x) = -2 + sin(1/x) - (1/x)cos(1/x)
For x > 0: f'(x) = 2 - sin(1/x) + (1/x)cos(1/x)

To check if f'(0) is defined, we would need to use the limit definition of the derivative at x=0. As x approaches 0, the term (1/x)cos(1/x) oscillates and does not approach a finite limit. Therefore, f'(0) is undefined.

New answer posted

4 months ago

0 Follower 3 Views

R
Raj Pandey

Contributor-Level 9

Given K_f = 1.85 K kg mol? ¹ for a solution with molality of 2 m.

ΔT_f = I * K_f * m

3.885 = I * 1.85 * 2

The van't Hoff factor, I = 1.05.

i = 1 + (n-1)α. For an electrolyte dissociating into 2 ions, n=2.

1.05 = 1 + (2-1)α.

The degree of dissociation, α = 0.05 or 50 * 10? ³.

New answer posted

4 months ago

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R
Raj Pandey

Contributor-Level 9

Please consider the following Image

 

New answer posted

4 months ago

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R
Raj Pandey

Contributor-Level 9

Please consider the following Image

 

New answer posted

4 months ago

0 Follower 5 Views

R
Raj Pandey

Contributor-Level 9

For an acidic buffer solution, pH = pKa + log ( [Base]/ [Acid]).

Given pH = 5.74 and pKa = 4.74.

5.74 = 4.74 + log ( [Base]/1).

1 = log ( [Base]).

[Base] = 10M.

New answer posted

4 months ago

0 Follower 2 Views

R
Raj Pandey

Contributor-Level 9

For the reaction C? H? → C? H? + H? , calculate the enthalpy change (ΔH).

ΔH = [Bond energy (C-C) + 6 * Bond energy (C-H)] - [Bond energy (C=C) + 4 * Bond energy (C-H) + Bond energy (H-H)]

ΔH = 347 + 2 (414) - 611 - 436 = 128 kJ/mol.

New answer posted

4 months ago

0 Follower 6 Views

R
Raj Pandey

Contributor-Level 9

Benzyl amine (0.1 mole) reacts with 3 equivalents of CH? Br to form Benzyl trimethyl ammonium bromide.

Given 23g of Benzyl trimethyl ammonium bromide (molar mass 230 g/mol ), which is 0.1 mol.

Therefore, moles of CH? Br = 0.3 = 3 x 10? ¹. The value of n is 3.

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